| 1256652-96-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1256652-96-6
• 化学式: C₆₀H₁₀₂O₁₂P₆Pt₃
• 分子量: 1786.55
• InChiKey: HDCQNOIIKDVGBM-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 以 氘代丙酮 为溶剂， 生成
  参考文献：
  名称：

  A Facile Approach toward Multicomponent Supramolecular Structures: Selective Self-Assembly via Charge Separation

  摘要：

  A novel approach toward the construction of multicomponent two-dimensional (2-D) and three-dimensional (3-D) metallosupramolecules is reported. Simply by mixing carboxylate and pyridyl ligands with cis-Pt(PEt3)(2)(OTf)(2) in a proper ratio, coordination-driven self-assembly occurs, allowing for the selective generation of discrete multicomponent structures via charge separation on the metal centers. Using this method, a variety of 2-D rectangles and 3-D prisms were prepared under mild conditions. Moreover, multicomponent self-assembly can also be achieved by supramolecule-to-supramolecule transformations. The products were characterized by P-31 and H-1 multinuclear NMR spectroscopy, electrospray ionization mass spectrometry, and pulsed-field-gradient spin echo NMR techniques together with computational simulations.

  DOI：

  10.1021/ja106251f
• 作为产物：
  描述：

  cis-[Pt(II)(PEt)₃(trifluoromethane-sulfonate)₂] 、 disodium terephthalate 以 水 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  A Facile Approach toward Multicomponent Supramolecular Structures: Selective Self-Assembly via Charge Separation

  摘要：

  A novel approach toward the construction of multicomponent two-dimensional (2-D) and three-dimensional (3-D) metallosupramolecules is reported. Simply by mixing carboxylate and pyridyl ligands with cis-Pt(PEt3)(2)(OTf)(2) in a proper ratio, coordination-driven self-assembly occurs, allowing for the selective generation of discrete multicomponent structures via charge separation on the metal centers. Using this method, a variety of 2-D rectangles and 3-D prisms were prepared under mild conditions. Moreover, multicomponent self-assembly can also be achieved by supramolecule-to-supramolecule transformations. The products were characterized by P-31 and H-1 multinuclear NMR spectroscopy, electrospray ionization mass spectrometry, and pulsed-field-gradient spin echo NMR techniques together with computational simulations.

  DOI：

  10.1021/ja106251f