9-(4'-methoxybiphenyl-4-yl)-9H-carbazole | 1229902-23-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(4'-methoxybiphenyl-4-yl)-9H-carbazole
• 英文别名: 9-[4-(4-methoxyphenyl)phenyl]carbazole
• CAS: 1229902-23-1
• 化学式: C₂₅H₁₉NO
• 分子量: 349.432
• InChiKey: JYNIKCBGTHAMTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  14.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  三溴化硼 、 9-(4'-methoxybiphenyl-4-yl)-9H-carbazole 在 氮气 、 盐酸 、 二氯甲烷 、 disodium;carbonate 、 水 、 乙醚 、 Brine 、 magnesium sulfate 、 silica gel 、 乙酸乙酯 、 乙醇 作用下， 以 二氯甲烷 为溶剂， 反应 20.0h， 生成 4'-(9H-carbazol-9-yl)-[1,1'-biphenyl]-4-ol
  参考文献：
  名称：

  Cross Linked Organic Conductive Layer

  摘要：

  本发明提供了在电子设备中形成交联导电聚合物层的各种化合物、组合物、方法和过程。

  公开号：

  US20110245429A1
• 作为产物：
  描述：

  9-(4-溴苯基)咔唑 在 Pd(PPh3)4 potassium carbonate 作用下， 以 1,4-二氧六环 、 水 为溶剂， 生成 9-(4'-methoxybiphenyl-4-yl)-9H-carbazole
  参考文献：
  名称：

  Cross Linked Organic Conductive Layer

  摘要：

  本发明提供了各种化合物、组合物、方法和过程，用于在电子设备中形成交联导电聚合层。

  公开号：

  US20110245429A1

文献信息

• FLUORENYLENE COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE USING SAME
  申请人：SAITOH AKIHITO

  公开号：US20070155998A1

  公开（公告）日：2007-07-05

  A novel pyrenylfluorenylene compound is provided which is represented by the general formula (1):

  提供一种新型的芘基芴烯化合物，其通式表示为(1):
• A novel electromagnetic mill promoted mechanochemical solid-state Suzuki–Miyaura cross-coupling reaction using ultra-low catalyst loading
  作者：Xin Li、Yunxia Liu、Lizhi Zhang、Yunhui Dong、Qing Liu、Daopeng Zhang、Lei Chen、Zengdian Zhao、Hui Liu

  DOI：10.1039/d2gc01427k

  日期：——

  The Nobel-prize-winning Suzuki–Miyaura cross-coupling (SMC) is a practical and attractive strategy for the construction of C–C bonds in both academic and industrial settings. However, the development of solid-state SMC reactions remains extremely scarce. Herein, we report an electromagnetic mill (EMM) promoted solid-state SMC reaction using ultra-low palladium loading (0.05 mol%) without any liquid

  获得诺贝尔奖的 Suzuki-Miyaura 交叉耦合 (SMC) 是一种实用且有吸引力的策略，用于在学术和工业环境中构建 C-C 键。然而，固态SMC反应的发展仍然极其稀缺。在此，我们报道了一种电磁磨 (EMM) 促进固态 SMC 反应，该反应使用超低钯负载量 (0.05 mol%) 而没有任何液体分子分散剂。该协议具有显着扩大的底物范围、良好的官能团耐受性、有效的克级合成，尤其是相对较高的产量。EMM条件可以抑制催化剂的高度聚集并加速固体反应物的混合，这可能是获得优异效率的关键。该策略的实用性体现在光致发光分子的修饰中，微溶化合物的交叉偶联和几种重要的生物活性分子的合成。这种固态 EMM-SMC 将有可能发展成为具有工业吸引力和环境友好的路线，本研究中开发的 EMM 系统可以为无溶剂固态金属催化合成各种有价值的目标打开广阔的化学空间领域。科学领域。
• Organic electroluminescent display device and chemical compounds for liquid crystals
  申请人：Kido Junji

  公开号：US20070164257A1

  公开（公告）日：2007-07-19

  The new organic electroluminescent display device has a carrier-transporting layer and/or an organic luminous layer composed of a nematic liquid crystal or a liquid crystal dispersing a carrier-transporting low-molecule therein. When the organic luminous layer is to be bestowed with faculty as a liquid crystal, it is made of a nematic liquid crystal. Both the carrier-transporting layer and the organic luminous layer may be bestowed with faculty as a liquid crystal. Since the liquid crystal is incorporated in the carrier-transporting layer and/or the organic luminous layer, the display device can be driven as a liquid crystal display device in a dark place by charging with a voltage lower than a light emission initiating potential. Of course, it is driven as an electroluminescent display device when it is charged with a voltage higher than the light emission initiating potential. Use of an electroluminescent liquid crystal as a organic luminous layer enables omission of a carrier-transporting layer.
• PYRENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE MAKING USE OF THE SAME
  申请人：Ito Mitsunori

  公开号：US20090058270A1

  公开（公告）日：2009-03-05

  Provided is an organic electroluminescence device including one or two or more organic thin-film layers having at least a light emitting layer interposed between a negative electrode and a positive electrode, in which the light emitting layer contains a pyrene derivative of a specified structure and an amine compound of a specified structure. The organic electroluminescence device excels in heat resistance, ensures long life and high luminous efficiency, and is capable of emitting blue, green and red lights.
• Organic Electroluminescent Display Device and Chemical Compounds for Liquid Crystals
  申请人：Kido Junji

  公开号：US20090058277A1

  公开（公告）日：2009-03-05

  The new organic electroluminescent display device has a carrier-transporting layer and/or an organic luminous layer composed of a nematic liquid crystal or a liquid crystal dispersing a carrier-transporting low-molecule therein. When the organic luminous layer is to be bestowed with faculty as a liquid crystal, it is made of a nematic liquid crystal. Both the carrier-transporting layer and the organic luminous layer may be bestowed with faculty as a liquid crystal. Since the liquid crystal is incorporated in the carrier-transporting layer and/or the organic luminous layer, the display device can be driven as a liquid crystal display device in a dark place by charging with a voltage lower than a light emission initiating potential. Of course, it is driven as an electroluminescent display device when it is charged with a voltage higher than the light emission initiating potential. Use of an electroluminescent liquid crystal as a organic luminous layer enables omission of a carrier-transporting layer.