(S)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-(1-hydroxymethyl-cyclopropyl)-methanol | 133463-10-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (S)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-(1-hydroxymethyl-cyclopropyl)-methanol
• CAS: 133463-10-2
• 化学式: C₁₀H₁₈O₄
• 分子量: 202.251
• InChiKey: IOZSGWFMZHXSJQ-HTQZYQBOSA-N

反应信息

• 作为产物：
  描述：

  (R)-(+)-2,2-二甲基-1,3-二氧戊环-4-甲醛 在 lithium aluminium tetrahydride 、 叔丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 生成 (S)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-(1-hydroxymethyl-cyclopropyl)-methanol
  参考文献：
  名称：

  Synthesis of 2-spirocyclopropylglucose via condensation of erythrose with the lithium enolate of 2,6-di-tert=butyl-4-methylphenyl cyclopropanecarboxylate

  摘要：

  Glyceraldehyde, erythrose, and threose are condensed with the enolate derived from cyclopropanecarboxylic acid BHT ester. The conversion of two diastereomeric products of this condensation into new 2-spirocyclopropyl-substituted aldopyranoses is described.

  DOI：

  10.1016/s0040-4039(00)79465-2