1-<(11S)-11-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-galactopyranosyl)-2,3,5,8,9-penta-O-acetyl-6,10-dideoxy-10-(tetradecanoyl)amino-α-L-galacto-D-allo-undecodialdo-1,4-furanose-11,7-pyranos-1-yl>uracil | 117299-98-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-<(11S)-11-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-galactopyranosyl)-2,3,5,8,9-penta-O-acetyl-6,10-dideoxy-10-(tetradecanoyl)amino-α-L-galacto-D-allo-undecodialdo-1,4-furanose-11,7-pyranos-1-yl>uracil
• CAS: 117299-98-6
• 化学式: C₅₃H₇₈N₄O₂₄
• 分子量: 1155.21
• InChiKey: DWTPPZYRWWUDLI-GGQXMYAVSA-N

物化性质

• 密度：
  1.32±0.1 g/cm3(Predicted)

反应信息

• 作为反应物：
  描述：

  1-<(11S)-11-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-galactopyranosyl)-2,3,5,8,9-penta-O-acetyl-6,10-dideoxy-10-(tetradecanoyl)amino-α-L-galacto-D-allo-undecodialdo-1,4-furanose-11,7-pyranos-1-yl>uracil 在 sodium methylate 作用下， 以 甲醇 为溶剂， 反应 0.75h， 以85%的产率得到1-<(11S)-11-O-(2-acetamido-2-deoxy-β-D-galactopyranosyl)-6,10-dideoxy-10-(tetradecanoyl)amino-α-L-galacto-D-allo-undecodialdo-1,4-furanose-11,7-pyranos-1-yl>uracil
  参考文献：
  名称：

  Synthesis of a 2-acetamido-2-deoxy-α-d-galactopyranosyl analogue of tunicamycin

  摘要：

  DOI：

  10.1016/0008-6215(88)85106-1
• 作为产物：
  描述：

  乙酸酐 、 1-<(11S)-11-O-(2-acetamido-2-deoxy-4,6-O-isopropylidene-β-D-galactopyranosyl)-6,10-dideoxy-10-(tetradecanoyl)amino-α-L-galacto-D-allo-undecodialdo-1,4-furanose-11,7-pyranos-1-yl>uracil 生成 1-<(11S)-11-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-galactopyranosyl)-2,3,5,8,9-penta-O-acetyl-6,10-dideoxy-10-(tetradecanoyl)amino-α-L-galacto-D-allo-undecodialdo-1,4-furanose-11,7-pyranos-1-yl>uracil
  参考文献：
  名称：

  Synthesis of a 2-acetamido-2-deoxy-α-d-galactopyranosyl analogue of tunicamycin

  摘要：

  DOI：

  10.1016/0008-6215(88)85106-1