| 1361030-17-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1361030-17-2
• 化学式: C₄₇H₆₆F₃N₅O₂₈
• 分子量: 1206.05
• InChiKey: BEAHLVTXYGDQEM-OEWKQXAMSA-N

反应信息

• 作为反应物：
  描述：

  在 吡啶 、 甲醇 、 水 、 sodium methylate 、 碳酸氢钠 、 sodium hydroxide 、 1,4-二巯基-2,3-丁二醇 作用下， 以 水 为溶剂， 反应 15.75h， 生成 3-aminopropyl 2-acetamido-2-deoxy-α-D-galactopyranosyl-(1->3)-[a-L-fucopyranosyl-(1->2)]-α-D-galactopyranosyl-(1->3)-2-acetamido-2-deoxy-α-D-galactopyranoside
  参考文献：
  名称：

  Block synthesis of A tetrasaccharides (types 1, 3, and 4) related to the human ABO blood group system

  摘要：

  Blood group A tetrasaccharides of different types have the same terminal trisaccharide fragment that allows using a block scheme in their synthesis. 3-Aminopropyl glycosides of tetrasaccharides GalNAc alpha 1-3(Fuc alpha 1-2)Gal beta 1-3GlcNAc beta (A type 1), GalNAc alpha 1-3(Fuc alpha 1-2)Gal beta 1-3GalNAc alpha (A type 3), and GalNAc alpha 1-3(Fuc alpha 1-2)Gal beta 1-3GalNAc beta (A type 4) were synthesised using acetylated Gal alpha 1-3(Fuc alpha 1-2)Gal trichloroacetimidate as a glycosyl donor at the key stage. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2011.12.013
• 作为产物：
  描述：

  在 溶剂黄146 作用下， 反应 1.0h， 以42%的产率得到
  参考文献：
  名称：

  Block synthesis of A tetrasaccharides (types 1, 3, and 4) related to the human ABO blood group system

  摘要：

  Blood group A tetrasaccharides of different types have the same terminal trisaccharide fragment that allows using a block scheme in their synthesis. 3-Aminopropyl glycosides of tetrasaccharides GalNAc alpha 1-3(Fuc alpha 1-2)Gal beta 1-3GlcNAc beta (A type 1), GalNAc alpha 1-3(Fuc alpha 1-2)Gal beta 1-3GalNAc alpha (A type 3), and GalNAc alpha 1-3(Fuc alpha 1-2)Gal beta 1-3GalNAc beta (A type 4) were synthesised using acetylated Gal alpha 1-3(Fuc alpha 1-2)Gal trichloroacetimidate as a glycosyl donor at the key stage. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2011.12.013