1,4-bis-iodoacetyl-benzene | 143255-94-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,4-bis-iodoacetyl-benzene
• 英文别名: 1,4-Bis-jodacetyl-benzol；p-Bis-jodacetyl-benzol；2-Iodo-1-[4-(2-iodoacetyl)phenyl]ethanone
• CAS: 143255-94-1
• 化学式: C₁₀H₈I₂O₂
• 分子量: 413.981
• InChiKey: GGBSATYZBUWYQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-bis-iodoacetyl-benzene 、 苯胺 在 乙醇 作用下， 生成 1,4-bis-(N-phenyl-glycyl)-benzene
  参考文献：
  名称：

  ÜberDi-和Tri-acetyl-benzol和p-Phenylen-di-glyoxal（43. MitteilungüberStickstoff-Heterocyclen）

  摘要：

  DOI：

  10.1002/hlca.19390220162
• 作为产物：
  描述：

  1,4-二乙酰苯 在 potassium iodate 、 硫酸 、 potassium iodide 作用下， 以 溶剂黄146 为溶剂， 反应 42.0h， 以99%的产率得到1,4-bis-iodoacetyl-benzene
  参考文献：
  名称：

  碘化钾-碘酸钾-硫酸体系直接碘化制备芳香碘乙酰基衍生物

  摘要：

  芳香族乙酰基衍生物与碘化钾和碘酸钾在乙酸中在硫酸存在下在室温下反应，以良好的收率得到碘乙酰基衍生物。

  DOI：

  10.1246/bcsj.65.1731

文献信息

• NOVEL RESPONSIVE POLYMER SYSTEM AND NANOHYBRID THIN FILMS
  申请人：Lu Jennifer

  公开号：US20120038249A1

  公开（公告）日：2012-02-16

  This disclosure discloses novel responsive polymers that comprise a rod segment and (or) a coil segment. This disclosure also discloses nanomaterial-polymer composite comprising the responsive polymers that are covalently linked with nanomaterials. Also disclosed are polymeric transducer materials and sensor systems that comprise the nanomaterial-polymer composite.
• POLY(IMIDE-AMIDE) COPOLYMER, A METHOD FOR PREPARING A POLY(IMIDE-AMIDE) COPOLYMER, AND AN ARTICLE INCLUDING A POLY(IMIDE-AMIDE) COPOLYMER
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20170121460A1

  公开（公告）日：2017-05-04

  A poly(imide-amide) copolymer, which is a product of a reaction between a diamine including an amide structural unit-containing oligomer represented by Chemical Formula 1 and a dianhydride represented by Chemical Formula 3: wherein, groups and variables in Chemical Formulae 1 and 3 are the same as described in the specification.
• TRANSPARENT POLYMER FILM AND ELECTRONIC DEVICE INCLUDING THE SAME
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20170145166A1

  公开（公告）日：2017-05-25

  A composition for preparing an organic/inorganic hybrid poly(amide-imide) copolymer including a poly(amide-imide) copolymer, a poly(amide-amic acid) copolymer, or a poly(amide-imide/amic acid) copolymer including a structural unit represented by Chemical Formula 1; and a structural unit represented by Chemical Formula 2, a structural unit represented by Chemical Formula 3, or a combination thereof, and a polyhedral oligomeric silsesquioxane including a functional group capable of forming a hydrogen bond: wherein in Chemical Formulae 1 to 3, A, B, D, and E are the same as defined in the detailed description.
• POLY(AMIDE-IMIDE) COPOLYMER FILM, AND DISPLAY DEVICE INCLUDING SAME
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20170183462A1

  公开（公告）日：2017-06-29

  A poly(amide-imide) copolymer film having a compressive modulus of greater than or equal to about 1.8 gigaPascals and a yellowness index of less than or equal to about 3, when measured according to an ASTM E313 standard.
• POLYIMIDE FILM, COMPOSITION FOR PREPARING POLYIMEDE FILM, AND DISPLAY DEVICE INCLUDING POLYIMIDE FILM
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20180148543A1

  公开（公告）日：2018-05-31

  A polyimide film having tensile modulus of greater than or equal to about 5 gigapascals, and yellowness index of less than 2.5, when measured at a thickness of the film between 50 micrometers to 100 micrometers, wherein the polyimide film is a reaction product of a combination including an aromatic dianhydride and an aromatic diamine, wherein the aromatic dianhydride includes 4,4′-oxydiphthalic anhydride.