sodium 2-hydroxy-4-methylquinolinate | 145236-94-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: sodium 2-hydroxy-4-methylquinolinate
• CAS: 145236-94-8
• 化学式: C₁₀H₈NO*Na
• 分子量: 181.169
• InChiKey: KASMUTDFEROAHH-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  {Ru(η3:η3-C10H16)Cl(μ-Cl)}2 、 sodium 2-hydroxy-4-methylquinolinate 以 丙酮 为溶剂， 生成 {Ru(η3:η3-C10H16)Cl(NC9H5(O)Me-4)} 、 {Ru(η3:η3-C10H16)Cl(NC9H5(O)Me-4)}
  参考文献：
  名称：

  Geometrical isomerism in 2-hydroxypyridinate and pyridine-2-thiolate complexes derived from the ruthenium(IV) bis(allyl) dimer [{Ru(η³: η³-C₁₀H₁₆)Cl(µ-Cl)}₂]

  摘要：

  Reaction of the ruthenium(IV) chloro-bridged dimer [{Ru(eta3:eta3-C10H16)Cl(mu-Cl)}2] with a range of 2-hydroxypyridinate and pyridine-2-thiolate ligands (HL = 2-hydroxypyridine, 6-chloro-2-hydroxypyridine, 2-hydroxy-6-methylpyridine,2-hydroxy-4-methylquinoline,8-hydroxyquinoline,pyrrolidin-2-one,quinoline-2-thiol and 6-methylpyridine-2-thiol) gives the neutral, chelate compounds [Ru(eta3:eta3-C10H16)Cl(L)] each of which exists as both axial and equatorial geometric isomers. These isomers. occur in varying ratios and may be distinguished by their characteristic H-1 NMR spectra. The X-ray crystal structures of eq-[Ru(eta3:eta3-C10H16)Cl{NC6H3(O)Cl-6}] and of eq-[Ru(eta3:eta3-C10H16)Cl(NC9H6S)] are reported.

  DOI：

  10.1039/dt9920002765