| 63287-98-9

• CAS: 63287-98-9
• 化学式: C₃₂H₂₈Cl₂N₄NiO₂
• 分子量: 630.196
• InChiKey: XOTOOYVRPKFPMS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 1-benzoyl-2-cinnamylidenehydrazine 以 乙醇 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Cobalt, nickel, and copper coordination compounds with 3-phenylpropenal benzoylhydrazone

  摘要：

  3-Phenylpropenal benzoylhydrazone (HL) reacts with cobalt, nickel, and copper chlorides, nitrates, and acetates to give coordination compounds MX2 center dot 2HL center dot nH(2)O [M = Co, Ni, Cu; X = Cl, NO3, HL = C6H5CH=CHCH=NNHC(O)C6H5; n = 0, 2] and ML2 center dot nH(2)O (M = Co, Ni, Cu; n = 1-3). Complexes MALCl (M = Co, Ni, Cu) were obtained by these reactions in the presence of amines (A = C5H5N, 2-CH3C5H4N, 3-CH3C5H4N, 4-CH3C5H4N). All the compounds have a monomeric structure. Azomethine (HL) in them behaves as a bidentate N,O-liaand. Thermolysis of the complexes involves the stages of dehydration (70-90 degrees C), deaquation (145-155 degrees C) or deamination (145-185 degrees C), and complete thermal decomposition (330-490 degrees C).

  DOI：

  10.1134/s1070363206100161