1-decyl-4-methylquinolin-1-ium iodide | 1428757-88-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 1-decyl-4-methylquinolin-1-ium iodide
• 英文别名: 1-decyl-4-methylquinolinium iodide
• CAS: 1428757-88-3
• 化学式: C₂₀H₃₀N*I
• 分子量: 411.369
• InChiKey: YAUGTASJGPKKCL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.58
• 重原子数：
  22.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  3.88
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1-decyl-4-methylquinolin-1-ium iodide 在 硫酸 、 sodium hydroxide 作用下， 以 水 为溶剂， 反应 2.0h， 生成 4-[(1-decyl-1H-quinolin-4-ylidenemethyl)azo]benzaldehyde
  参考文献：
  名称：

  NLO chromophores containing dihydrobenzothiazolylidene and dihydroquinolinylidene donors with an azo linker: Synthesis and optical properties

  摘要：

  We report the synthesis of a series of nonlinear optical chromophores containing either - a dihydrobenzothiazolylidene or dihydroquinolinylidene donor with an azo linker. The results demonstrate the versatility of coupling a diazonium salt to a donor-methylidene nucleus in order to access novel materials with good thermal stabilities and high nonlinear optical responses. From hyper-Raleigh scattering studies it was found that the use of the well-known TCF acceptor yields the best performing chromophores, one of which has a dynamic first hyperpolarizability of 1900 x 10(-30) esu at 800 nm. The results from this study suggest the use of pro-aromatic donors such as dihydrobenzothiazolylidene or dihydroquinolinylidene results in compounds with higher nonlinear optical responses than those containing donors based on either indoline or aniline. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.01.010
• 作为产物：
  描述：

  4-甲基喹啉 、 1-碘癸烷 反应 72.0h， 以100%的产率得到1-decyl-4-methylquinolin-1-ium iodide
  参考文献：
  名称：

  NLO chromophores containing dihydrobenzothiazolylidene and dihydroquinolinylidene donors with an azo linker: Synthesis and optical properties

  摘要：

  We report the synthesis of a series of nonlinear optical chromophores containing either - a dihydrobenzothiazolylidene or dihydroquinolinylidene donor with an azo linker. The results demonstrate the versatility of coupling a diazonium salt to a donor-methylidene nucleus in order to access novel materials with good thermal stabilities and high nonlinear optical responses. From hyper-Raleigh scattering studies it was found that the use of the well-known TCF acceptor yields the best performing chromophores, one of which has a dynamic first hyperpolarizability of 1900 x 10(-30) esu at 800 nm. The results from this study suggest the use of pro-aromatic donors such as dihydrobenzothiazolylidene or dihydroquinolinylidene results in compounds with higher nonlinear optical responses than those containing donors based on either indoline or aniline. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.01.010

文献信息

• The third-order nonlinear optical properties of charge flowable trimethine cyanine with quinolone groups
  作者：Jia-Tao Miao、Xing-Zhi Wu、Ru Sun、Ying-Lin Song、Jian-Feng Ge

  DOI：10.1016/j.dyepig.2014.01.014

  日期：2014.6

  Organic molecules with charge flow abilities gain much attention in third-order nonlinear optical materials. To evaluate the hypothesis of terminal donor and/or acceptor groups participating organic resonance structures for third-order nonlinear optical materials, conjugated double bonds structures with terminal amino groups are selected in this paper. The trimethine cyanine dye with quinolone skeleton (3a) was synthesized, it shows strong reverse saturable absorption and nonlinear refraction in dimethyl formamide solution at 532 nm. Then, its derivative compound (3b) with long alkyl chains was synthesized in order to improve the film forming performance, the spinning coating thin film exhibits strong reverse saturable absorption with the third-order nonlinear susceptibilities x(I)((3)) = 3.42 x 10(-8) esu and chi((3)) = 3.23 x 10(-9) esu under nanosecond and picosecond laser beams respectively. The results validate that the organic compounds with terminal donor and/or acceptor groups participating resonance structures have potential value for the design of the third-order nonlinear optical materials. (c) 2014 Elsevier Ltd. All rights reserved.