1,4-dimethoxy-6,7,10,11-tetrakis(decyloxy)triphenylene | 249922-90-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1,4-dimethoxy-6,7,10,11-tetrakis(decyloxy)triphenylene
• 英文别名: 6,7,10,11-tetrakis-decoxy-1,4-dimethoxytriphenylene
• CAS: 249922-90-5
• 化学式: C₆₀H₉₆O₆
• 分子量: 913.419
• InChiKey: BNECGSSKFFPVPU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  22.7
• 重原子数：
  66
• 可旋转键数：
  42
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,4-dimethoxy-6,7,10,11-tetrakis(decyloxy)triphenylene 在 ammonium cerium(IV) nitrate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 2.0h， 生成 6,7,10,11-tetrakis(decyloxy)triphenylene-1,4-dione
  参考文献：
  名称：

  Synthesis and Characterization of Triphenylene-Dione Half-Disc Mesogens

  摘要：

  Novel half-disc mesogens of general structure 6,7,10,11-tetrakis(alkoxy)triphenylene-1,4-dione were synthesized and their phases characterized by polarized microscopy, differential scanning calorimetry and X-ray diffraction. These compounds were found to form hexagonal columnar mesophases upon heating, despite their half-disc molecular shapes. X-ray diffraction suggests that within the mesophases a dimeric mesogenic subunit exists, driven by dipolar forces, in which the molecules are oriented antiparallel to one another. Such a dimer is approximately disc-shaped, and may explain the formation of columnar phases by these half-disc molecules.

  DOI：

  10.1080/15421400490435396
• 作为产物：
  描述：

  1,2-(二葵氧荃)苯 在 硫酸 、 碘 、 三氯化铁 、 碘酸 、 铜 作用下， 以 氯仿 、 水 、 溶剂黄146 为溶剂， 反应 5.0h， 生成 1,4-dimethoxy-6,7,10,11-tetrakis(decyloxy)triphenylene
  参考文献：
  名称：

  Synthesis and Characterization of Triphenylene-Dione Half-Disc Mesogens

  摘要：

  Novel half-disc mesogens of general structure 6,7,10,11-tetrakis(alkoxy)triphenylene-1,4-dione were synthesized and their phases characterized by polarized microscopy, differential scanning calorimetry and X-ray diffraction. These compounds were found to form hexagonal columnar mesophases upon heating, despite their half-disc molecular shapes. X-ray diffraction suggests that within the mesophases a dimeric mesogenic subunit exists, driven by dipolar forces, in which the molecules are oriented antiparallel to one another. Such a dimer is approximately disc-shaped, and may explain the formation of columnar phases by these half-disc molecules.

  DOI：

  10.1080/15421400490435396

文献信息

• Emissive polymers and devices incorporating these polymers
  申请人：Massachusetts Institute of Technology

  公开号：US20030178607A1

  公开（公告）日：2003-09-25

  The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or &pgr;-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

  本发明涉及一类具有色团的发光和导电聚合物组合物，特别是这些组合物的固体薄膜表现出增加的发光寿命、量子产率和放大的发射。通过具有刚性基团的聚合物，可以提供这些理想的性质，以防止聚合物在固化时重新组织、聚集或π-堆积。这些聚合物还可以显示出相对于溶剂和热暴露的异常高稳定性。本发明还涉及一种通过这些聚合物的发光和导电性质来感测分析物的传感器和方法。通过在聚合物表面激活色团，可以感测分析物。分析物包括芳香族、磷酸酯基团和特别是气态炸药和化学战剂。本发明还涉及通过将具有能量迁移通路的聚合物并入或将聚合物作为块共聚物或多层的装置和方法来放大发射。
• EMISSIVE POLYMERS AND DEVICES INCORPORATING THESE POLYMERS
  申请人：Swager Timothy M.

  公开号：US20110175035A1

  公开（公告）日：2011-07-21

  The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

  本发明涉及一类具有色团的发光和导电聚合物组合物，特别是这些组合物的固体薄膜表现出增强的发光寿命、量子产率和放大的发射。这些理想的性质可以通过具有刚性基团的聚合物来实现，以防止聚合物在固化时重新组织、聚集或π-堆积。这些聚合物还可以表现出与溶剂和热暴露相关的非常高的稳定性。本发明还涉及一种传感器和一种通过这些聚合物的发光和导电性能来感测分析物的方法。通过激活聚合物表面的色团来感测分析物。分析物包括芳香族化合物、磷酸酯基团和特别是气态炸药和化学战剂。本发明还涉及通过将具有能量迁移途径的聚合物纳入到块共聚物或多层中来放大发射的装置和方法。
• US7208122B2
  申请人：——

  公开号：US7208122B2

  公开（公告）日：2007-04-24
• US7393503B2
  申请人：——

  公开号：US7393503B2

  公开（公告）日：2008-07-01
• US7662309B2
  申请人：——

  公开号：US7662309B2

  公开（公告）日：2010-02-16