α-myrcenol acetate | 80348-75-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: α-myrcenol acetate
• 英文别名: 7-methyl-3-methylene-7-octenyl acetate；(7-Methyl-3-methylideneoct-7-enyl) acetate
• CAS: 80348-75-0
• 化学式: C₁₂H₂₀O₂
• 分子量: 196.29
• InChiKey: GAERHTNIPMRGTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-(bromomethyl)but-3-enal diethyl acetal 在 吡啶 、 sodium tetrahydroborate 、 copper(l) iodide 、 4-甲基苯磺酸吡啶 、 草酸 、 sodium hydroxide 、 亚磷酸三乙酯 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 37.33h， 生成 α-myrcenol acetate
  参考文献：
  名称：

  7-METHYL-3-METHYLENE-7-OCTENAL ACETAL COMPOUND AND METHODS FOR PRODUCING ALDEHYDE COMPOUND AND ESTER COMPOUND USING THE SAME

  摘要：

  提供了一种有效生产化合物的方法，例如圣何塞蚜虫的性信息素。例如，提供了一种生产7-甲基-3-亚甲基-7-辛烯基羧酸酯化合物（4）的方法，该方法包括以下步骤：水解7-甲基-3-亚甲基-7-辛烯醛缩合物（1）以获得7-甲基-3-亚甲基-7-辛烯醛（2）；还原7-甲基-3-亚甲基-7-辛烯醛（2）以获得7-甲基-3-亚甲基-7-辛烯醇（3）；酯化7-甲基-3-亚甲基-7-辛烯醇（3）以获得7-甲基-3-亚甲基-7-辛烯基羧酸酯化合物（4）。

  公开号：

  US20180155267A1

文献信息

• COMPOSITION HAVING SEX PHEROMONE ACTIVITY ON SAN JOSE SCALE, AND ATTRACTANT, MATING DISRUPTANT, ATTRACTION METHOD AND MATING DISRUPTION METHOD FOR SAN JOSE SCALE
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3504968A1

  公开（公告）日：2019-07-03

  There are provided a composition containing a substance having sex pheromone activity on San Jose scale (SJS) after finding the substance. More specifically, there are provided a composition having sex pheromone activity on SJS, the composition containing 3,7-dimethyl-7-octenyl propionate as a substance having sex pheromone activity on SJS; an attractant for SJS, the attractant containing the composition and a support for supporting the composition in such a manner as to allow the substance to be released; a mating disruptant for SJS, the disruptant containing the composition and a container for storing the composition in such a manner as to allow the substance to be released; and a method for attracting SJS or disrupting mating of SJS, the method including a step of installing the attractant or the mating disruptant for SJS in a field to release the substance from the attractant or the mating disruptant into the field.

  本发明提供了一种组合物，该组合物含有一种在圣何塞量表（SJS）上发现后具有性信息素活性的物质。更具体地说，提供了一种对圣何塞鳞片具有性信息素活性的组合物，该组合物含有对圣何塞鳞片具有性信息素活性的物质--3,7-二甲基-7-辛烯基丙酸酯；一种圣何塞鳞片的引诱剂，该引诱剂含有该组合物，以及一种以允许该物质释放的方式支撑该组合物的支架；一种用于 SJS 的交配干扰物，该干扰物含有该组合物和一个用于以允许该物质释放的方式储存该组合物的容器；以及一种用于吸引 SJS 或干扰 SJS 交配的方法，该方法包括一个步骤，即在田地中安装用于 SJS 的吸引物或交配干扰物，以将该物质从吸引物或交配干扰物释放到田地中。
• 7-methyl-3-methylene-7-octenal acetal compound and methods for producing aldehyde compound and ester compound using the same
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10611718B2

  公开（公告）日：2020-04-07

  There are provided methods of efficiently producing compounds that are, for example, sex pheromones of San Jose Scale. For example, there is provided a method for producing a 7-methyl-3-methylene-7-octenyl carboxylate compound (4), the method including the steps of: hydrolyzing a 7-methyl-3-methylene-7-octenal acetal compound (1) to obtain 7-methyl-3-methylene-7-octenal (2); reducing the 7-methyl-3-methylene-7-octenal (2) to obtain 7-methyl-3-methylene-7-octenol (3); and esterifying the 7-methyl-3-methylene-7-octenol (3) to obtain a 7-methyl-3-methylene-7-octenyl carboxylate compound (4).

  本发明提供了高效生产圣何塞鳞片性信息素等化合物的方法。例如，提供了一种生产 7-甲基-3-亚甲基-7-辛烯羧酸酯化合物（4）的方法，该方法包括以下步骤：水解 7-甲基-3-亚甲基-7-辛烯醛缩醛化合物 (1)，得到 7-甲基-3-亚甲基-7-辛烯醛 (2)；还原 7-甲基-3-亚甲基-7-辛烯醛 (2)，得到 7-甲基-3-亚甲基-7-辛烯醇 (3)；以及酯化 7-甲基-3-亚甲基-7-辛烯醇 (3)，得到 7-甲基-3-亚甲基-7-辛烯羧酸酯化合物 (4)。
• Composition having sex pheromone activity on San Jose scale, and attractant, mating disruptant, attraction method and mating disruption method for San Jose scale
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10736317B2

  公开（公告）日：2020-08-11

  A composition containing a substance having sex pheromone activity on San Jose scale (SJS) after finding the substance. More specifically, there are provided a composition having sex pheromone activity on SJS, the composition containing 3,7-dimethyl-7-octenyl propionate as a substance having sex pheromone activity on SJS; an attractant for SJS, the attractant containing the composition and a support for supporting the composition in such a manner as to allow the substance to be released; a mating disruptant for SJS, the disruptant containing the composition and a container for storing the composition in such a manner as to allow the substance to be released; and a method for attracting SJS or disrupting mating of SJS, the method including a step of installing the attractant or the mating disruptant for SJS in a field to release the substance from the attractant or the mating disruptant into the field.

  一种含有对圣何塞尺度（SJS）具有性信息素活性的物质的组合物。更具体地说，提供了一种对圣何塞鳞片具有性信息素活性的组合物，该组合物含有作为对圣何塞鳞片具有性信息素活性的物质的 3,7-二甲基-7-辛烯基丙酸酯；一种圣何塞鳞片的引诱剂，该引诱剂含有该组合物和一种支撑物，该支撑物用于以允许该物质释放的方式支撑该组合物；一种用于 SJS 的交配干扰物，该干扰物含有该组合物和一个用于以允许该物质释放的方式储存该组合物的容器；以及一种用于吸引 SJS 或干扰 SJS 交配的方法，该方法包括一个步骤，即在田地中安装用于 SJS 的吸引物或交配干扰物，以将该物质从吸引物或交配干扰物释放到田地中。
• Synthesis of ?-myrcenol acetate and propionate from isobutenylcarbinol
  作者：V. V. Veselovskii、S. P. Skorobogatov、M. A. Novikova、A. M. Moiseenkov

  DOI：10.1007/bf00959574

  日期：1990.3
• 7-METHYL-3-METHYLENE-7-OCTENAL ACETAL COMPUND AND METHODS FOR PRODUCING ALDEHYDE COMPOUND AND ESTER COMPOUND USING THE SAME
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20200181059A1

  公开（公告）日：2020-06-11

  There are provided methods of efficiently producing compounds that are, for example, sex pheromones of San Jose Scale. For example, there is provided a method for producing a 7-methyl-3-methylene-7-octenyl carboxylate compound (4), the method including the steps of: hydrolyzing a 7-methyl-3-methylene-7-octenal acetal compound (1) to obtain 7-methyl-3-methylene-7-octenal (2); reducing the 7-methyl-3-methylene-7-octenal (2) to obtain 7-methyl-3-methylene-7-octenol (3); and esterifying the 7-methyl-3-methylene-7-octenol (3) to obtain a 7-methyl-3-methylene-7-octenyl carboxylate compound (4).