| 144496-89-9

• CAS: 144496-89-9
• 化学式: C₂₈H₃₀Fe₂N₄PdS₄
• 分子量: 768.951
• InChiKey: SHAARMKVSGMXRA-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 methyl 2-(1-ferrocenylethylidene)hydrazinecarbodithioate 以 乙醇 为溶剂， 以73%的产率得到
  参考文献：
  名称：

  Syntheses, electrochemistry and crystal structure studies of novel cis-configuration biferrocene trinuclear complexes

  摘要：

  The syntheses and characterization of novel biferrocene trinuclear complexes for Schiff base ligand, S-methyl-N-(ferrocenyl-1-methyl-methylidene)dithiocarbazate thereafter abbreviate as HL), are described. X-ray diffraction studies established the structures of the palladium complex, PdL2 2 and the copper complex, CuL2 3. The geometry of Pd(II) in 2 is close to square planar and in novel cis-configuration with two ferrocene moieties in the same side, while that of Cu(II) in 3 is close to tetrahedral configuration. Electrochemical measurements suggest that the distorted square planar configuration of the Ni(II) and Pd(II) moieties, can effectively transmit the redox effects of the ferrocene moieties, while the distorted tetrahedral configuration of Cu(II) complex can not transmit the redox effects. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00583-x