9-[4,6-bis(2-chloroethoxy)-1,3,5-triazin-2-yl]-9H-carbazole | 1620749-93-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-[4,6-bis(2-chloroethoxy)-1,3,5-triazin-2-yl]-9H-carbazole
• 英文别名: 9-[4,6-Bis(2-chloroethoxy)-1,3,5-triazin-2-yl]-9 h-carbazole；9-[4,6-bis(2-chloroethoxy)-1,3,5-triazin-2-yl]carbazole
• CAS: 1620749-93-0
• 化学式: C₁₉H₁₆Cl₂N₄O₂
• 分子量: 403.268
• InChiKey: QTJKOCGBQCHPTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  62.1
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  9-[4,6-bis(2-chloroethoxy)-1,3,5-triazin-2-yl]-9H-carbazole 、 2-(2'-cyanoethylthio)-3,6,7-tris(methylthio)tetrathiafulvalene 在 potassium hydroxide 作用下， 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 6.5h， 以71%的产率得到9-[4,6-bis({2-[4',5,5'-tris(methylsulfanyl)tetrathiafulvalen-4-yl]sulfanyl}ethoxy)-1,3,5-triazin-2-yl]-9H-carbazole
  参考文献：
  名称：

  New Tetrathiafulvalenes Containing Carbazole and 1,3,5-Triazine Fragments: Synthesis, Electro-Chemical and Optical Properties

  摘要：

  New tetrathiafulvalenes, containing carbazole and 1,3,5-triazine fragments added to the tetrathia-fulvalene ring by means of a S-CH2-CH2-O bridge, were synthesized. The electrochemical properties of the initial compounds and of the final products were investigated by cyclic voltammetry. The optical characteristics of their solutions were studied by UV absorption spectroscopy and fluorescence spectroscopy.

  DOI：

  10.1007/s10593-014-1522-3
• 作为产物：
  描述：

  咔唑 在 正丁基锂 、 potassium carbonate 作用下， 以 四氢呋喃 、 正己烷 、 丙酮 为溶剂， 反应 17.0h， 生成 9-[4,6-bis(2-chloroethoxy)-1,3,5-triazin-2-yl]-9H-carbazole
  参考文献：
  名称：

  New Tetrathiafulvalenes Containing Carbazole and 1,3,5-Triazine Fragments: Synthesis, Electro-Chemical and Optical Properties

  摘要：

  New tetrathiafulvalenes, containing carbazole and 1,3,5-triazine fragments added to the tetrathia-fulvalene ring by means of a S-CH2-CH2-O bridge, were synthesized. The electrochemical properties of the initial compounds and of the final products were investigated by cyclic voltammetry. The optical characteristics of their solutions were studied by UV absorption spectroscopy and fluorescence spectroscopy.

  DOI：

  10.1007/s10593-014-1522-3