3-azidopropyl α-L-arabinofuranosyl-(1->3)-β-D-galactopyranosyl-(1->6)-β-D-galactopyranosyl-(1->6)-[α-L-arabinofuranosyl-(1->3)]-β-D-galactopyranosyl-(1->6)-β-D-galactopyranoside | 1190749-54-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-azidopropyl α-L-arabinofuranosyl-(1->3)-β-D-galactopyranosyl-(1->6)-β-D-galactopyranosyl-(1->6)-[α-L-arabinofuranosyl-(1->3)]-β-D-galactopyranosyl-(1->6)-β-D-galactopyranoside
• CAS: 1190749-54-2
• 化学式: C₃₇H₆₃N₃O₂₉
• 分子量: 1013.91
• InChiKey: BODYIRFCLXMEGE-WIMJLCSOSA-N

反应信息

• 作为反应物：
  描述：

  3-azidopropyl α-L-arabinofuranosyl-(1->3)-β-D-galactopyranosyl-(1->6)-β-D-galactopyranosyl-(1->6)-[α-L-arabinofuranosyl-(1->3)]-β-D-galactopyranosyl-(1->6)-β-D-galactopyranoside 在 10% palladium on activated carbon 、 氢气 作用下， 以 水 为溶剂， 反应 2.0h， 以86%的产率得到3-aminopropyl α-L-arabinofuranosyl-(1->3)-β-D-galactopyranosyl-(1->6)-β-D-galactopyranosyl-(1->6)-[α-L-arabinofuranosyl-(1->3)]-β-D-galactopyranosyl-(1->6)-β-D-galactopyranoside
  参考文献：
  名称：

  Synthesis of 3,6-branched arabinogalactan-type tetra- and hexasaccharides for characterization of monoclonal antibodies

  摘要：

  Synthesis of tetra- and hexasaccharides built up from a beta-(1 -> 6)-linked galactopyranosyl backbone with arabinofuranosyl side chains at position 3 and with a 3-aminopropyl spacer related to arabinogalactans is described. These oligosaccharides were prepared for investigation of monoclonal antibodies raised against arabinogalactan proteins (AGPs) from pressed juice of Echinacea purpurea. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2009.04.025
• 作为产物：
  描述：

  3-azidopropyl 2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)-6-O-acetyl-2,4-di-O-benzoyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-1-thio-β-D-galactopyranosyl-(1->6)-[2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl-(1->3)]-2,4-di-O-benzoyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-β-D-galactopyranoside 在 sodium methylate 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 24.0h， 以86%的产率得到3-azidopropyl α-L-arabinofuranosyl-(1->3)-β-D-galactopyranosyl-(1->6)-β-D-galactopyranosyl-(1->6)-[α-L-arabinofuranosyl-(1->3)]-β-D-galactopyranosyl-(1->6)-β-D-galactopyranoside
  参考文献：
  名称：

  Synthesis of 3,6-branched arabinogalactan-type tetra- and hexasaccharides for characterization of monoclonal antibodies

  摘要：

  Synthesis of tetra- and hexasaccharides built up from a beta-(1 -> 6)-linked galactopyranosyl backbone with arabinofuranosyl side chains at position 3 and with a 3-aminopropyl spacer related to arabinogalactans is described. These oligosaccharides were prepared for investigation of monoclonal antibodies raised against arabinogalactan proteins (AGPs) from pressed juice of Echinacea purpurea. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2009.04.025