10-methyl-10H-spiro[acridine-9,1'-cyclohexane] | 1290129-49-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 10-methyl-10H-spiro[acridine-9,1'-cyclohexane]
• 英文别名: 10-methylspiro[acridine-9,1'-cyclohexane]
• CAS: 1290129-49-5
• 化学式: C₁₉H₂₁N
• 分子量: 263.382
• InChiKey: RVRVOFUDYDUYBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-bromo-N-methyl-N-phenylaniline 在 正丁基锂 、 硫酸 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 2.08h， 生成 10-methyl-10H-spiro[acridine-9,1'-cyclohexane]
  参考文献：
  名称：

  通过硝基酯和硝胺的光解裂解检测爆炸物

  摘要：

  含有硝胺的炸药 RDX 和含有硝基酯的炸药 PETN 被证明在暴露于阳光下时容易发生光致碎裂。含有硝基酯和硝胺部分的模型化合物也显示在暴露于紫外线照射时会碎裂。这种光裂解的产物是反应性的、亲电子的 NO x物质，例如亚硝酸和硝酸、一氧化氮和二氧化氮。N , N -二甲基苯胺能够被RDX 和 PETN的反应性亲电子 NO x光裂解产物硝化。一系列 9,9-二取代的 9,10-二氢吖啶 (DHAs) 由N-苯基邻氨基苯甲酸甲酯或二苯胺衍生物，同样显示出被 RDX 和 PETN 的光致碎裂产物快速硝化。由于荧光供体-受体发色团的产生，在 DHA 硝化时观察到 550 nm 处的新（开启）发射信号。使用荧光光谱法，约的存在。1.2 ng 的 RDX 和 320 pg 的 PETN 可以通过暴露在阳光下的固态 DHA 指示剂检测到。RDX 和 PETN 的光致碎裂产物对芳香胺的硝化是一种独特的、高度

  DOI：

  10.1021/jo200280c

文献信息

• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ORGANIQUES ÉLECTROLUMINESCENTS ET DISPOSITIF ORGANIQUE ÉLECTROLUMINESCENT LES UTILISANT
  申请人：GRACEL DISPLAY INC

  公开号：WO2010050781A1

  公开（公告）日：2010-05-06

  Disclosed Provided are a novel organic electroluminescent compound and an organic electroluminescent device using the same as an electroluminescent material. The disclosed organic electroluminescent compound is represented by Chemical Formula 1: (Formula I should be inserted here) wherein Ar1 represents (C6-C60)arylene, (C3~C60)heteroarylene containing one or more heteroatom(s) selected from N, O and S, 5- or 6-membered heterocycloalkylene containing one or more heteroatom(s) selected from N, O and S, (C3-C60)cycloalkylene, adamantylene, (C7-C60)bicycloalkylene, (C2-C60)alkenylene, (C2-C60)alkynylene, (Cl-C60)alkylenethio, (Cl-C60)alkyleneoxy, (C6-C60)aryleneoxy, (C6-C60)arylenethio or; (Formula II should be inserted here) and ring A and ring B independently represent a 5- to 7-membered heterocyclic amino group or a ring selected from the following structures: (Formula III should be inserted here) wherein the 5- to 7-membered heterocyclic amino group may further contain NR2I or one or more heteroatom(s) selected from O and S. The organic electroluminescent compound provides superior luminous efficiency and excellent life property. Therefore, it may be used to manufacture OLED devices having very good operation life.

  公开了一种新颖的有机电致发光化合物及使用该化合物作为电致发光材料的有机电致发光器件。所公开的有机电致发光化合物由化学式1表示：其中Ar1代表(C6-C60)芳基、(C3~C60)含有来自N、O和S的一个或多个杂原子的杂芳基、含有来自N、O和S的一个或多个杂原子的5-或6-成员杂环烷基、(C3-C60)环烷基、金刚烷基、(C7-C60)双环烷基、(C2-C60)烯烃基、(C2-C60)炔基、(Cl-C60)硫代烷基、(Cl-C60)氧代烷基、(C6-C60)氧代芳基、(C6-C60)硫代芳基或；环A和环B分别表示5-至7-成员杂环氨基或从以下结构中选择的环：其中5-至7-成员杂环氨基可能进一步包含NR2I或来自O和S的一个或多个杂原子。该有机电致发光化合物提供优越的发光效率和出色的寿命特性。因此，它可用于制造具有非常良好运行寿命的OLED器件。
• DETECTION OF ANALYTES INCLUDING NITRO-CONTAINING ANALYTES
  申请人：Swager Timothy M.

  公开号：US20130065318A1

  公开（公告）日：2013-03-14

  Sensors and methods for determination of analytes are provided. Analytes including explosives (e.g., RDX or PETN) may be determined by monitoring, for example, a change in an optical signal of a material upon exposure to the analyte. In some embodiments, the analyte and the material may interact via a chemical reaction to form a new emissive species. Embodiments described herein may provide inexpensive sensors with high selectivity and sensitivity.

  提供了用于测定分析物的传感器和方法。例如，可以通过监测物质在暴露于分析物（例如RDX或PETN）时的光信号变化来确定分析物。在某些实施例中，分析物和物质可以通过化学反应相互作用以形成新的发射物种。本文所述的实施例可能提供价格便宜、选择性和灵敏度高的传感器。
• Detection of analytes including nitro-containing analytes
  申请人：Swager Timothy M.

  公开号：US08999722B2

  公开（公告）日：2015-04-07

  Sensors and methods for determination of analytes are provided. Analytes including explosives (e.g., RDX or PETN) may be determined by monitoring, for example, a change in an optical signal of a material upon exposure to the analyte. In some embodiments, the analyte and the material may interact via a chemical reaction to form a new emissive species. Embodiments described herein may provide inexpensive sensors with high selectivity and sensitivity.

  提供用于确定分析物的传感器和方法。可以通过监测材料在暴露于分析物时的光信号变化来确定爆炸物（例如，RDX或PETN）等分析物。在某些实施例中，分析物和材料可以通过化学反应相互作用以形成新的发射物种。本文描述的实施例可以提供价格低廉、选择性和灵敏度高的传感器。
• Novel organic electroluminescent compounds and organic electroluminescent device using the same
  申请人：Gracel Display Inc.

  公开号：EP2182038A1

  公开（公告）日：2010-05-05

  Provided are a novel organic electroluminescent compound and an organic electroluminescent device using the same as an electroluminescent material. The disclosed organic electroluminescent compound is represented by Chemical Formula 1: wherein Ar1 represents (C6-C60)arylene, (C3-C60)heteroarylene containing one or more heteroatom(s) selected from N, O and S, 5- or 6-membered heterocycloalkylene containing one or more heteroatom(s) selected from N, O and S, (C3-C60)cycloalkylene, adamantylene, (C7-C60)bicycloalkylene, (C2-C60)alkenylene, (C2-C60)alkynylene, (C1-C60)alkylenethio, (C1-C60)alkyleneoxy, (C6-C60)aryleneoxy, (C6-C60)arylenethio or and ring A and ring B independently represent a 5- to 7-membered heterocyclic amino group or a ring selected from the following structures: wherein the 5- to 7-membered heterocyclic amino group may further contain NR21 or one or more heteroatom(s) selected from O and S.

  本文提供了一种新型有机电致发光化合物和一种使用该化合物作为电致发光材料的有机电致发光装置。所公开的有机电致发光化合物由化学式 1 表示： 其中 Ar1 代表(C6-C60)芳基烯、含有一个或多个选自 N、O 和 S 的杂原子的(C3-C60)杂芳基烯、含有一个或多个选自 N、(C3-C60)cycloalkylene, adamantylene, (C7-C60)bicycloalkylene, (C2-C60)alkenylene, (C2-C60)alkynylene, (C1-C60)alkylenethio, (C1-C60)alkyleneoxy, (C6-C60)aryleneoxy, (C6-C60)arylenethio 或 且 环 A 和环 B 独立地代表 5 至 7 元杂环氨基或选自以下结构的环： 其中 5 至 7 元杂环氨基可进一步含有 NR21 或一个或多个选自 O 和 S 的杂原子。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20170149007A1

  公开（公告）日：2017-05-25

  An organic EL device includes a pair of electrodes and an organic compound layer between pair of electrodes. The organic compound layer includes an emitting layer including a first material and a second material. The second material is a fluorescent material. Singlet energy EgS(H) of the first material and singlet energy EgS(D) of the second material satisfy a relationship of the following formula (1). The first material satisfies a relationship of the following formula (2) in terms of a difference ΔST(H) between the singlet energy EgS(H) and an energy gap Eg 77K (H) at 77K. EgS( H )>EgS( D )  (1) Δ ST ( H )=EgS( H )−Eg 77K ( H )<0.3 (eV)  (2)