1,1,1,2,2,4,4,5,5,6,6-Undecafluorohexan-3-one | 157337-62-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1,1,2,2,4,4,5,5,6,6-Undecafluorohexan-3-one
• CAS: 157337-62-7
• 化学式: C₆HF₁₁O
• 分子量: 298.056
• InChiKey: UIKPYMRWUBRHQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1,1,1,2,2,4,4,5,5,6,6-Undecafluorohexan-3-one 在 水 作用下， 生成 1,1,1,2,2,4,4,5,5,6,6-Undecafluoro-hexane-3,3-diol
  参考文献：
  名称：

  Saloutina; Zapevalov; Kodess, Russian Journal of Nondestructive Testing, 1997, vol. 33, # 2, p. 265 - 272

  摘要：

  DOI：
• 作为产物：
  描述：

  6H-全氟-1-己烯 在 sodium hypochlorite 、 五氟化锑 、 cesium fluoride 作用下， 以 乙腈 为溶剂， 反应 24.0h， 生成 1,1,1,2,2,4,4,5,5,6,6-Undecafluorohexan-3-one
  参考文献：
  名称：

  Saloutina, L. V.; Kodess, M. I.; Zapevalov, A. Ya., Russian Journal of Organic Chemistry, 1993, vol. 29, # 7.1, p. 1097 - 1107

  摘要：

  DOI：

文献信息

• Composition comprising fluorine-containing ketone
  申请人：Sinochem Lantian Co., Ltd

  公开号：US10953256B2

  公开（公告）日：2021-03-23

  Disclosed is a composition comprising: (A) at least one fluorine-containing ketone; and (B) an effective amount of stabilizer which is selected from at least one of the group consisting of an epoxy compound, a nitro compound, a hindered phenolic compound, a β-diketone compound, a phosphite compound, a salicylate compound, a cinnamate compound, a hydroxybenzophenone compound, a hydroxybenzoic acid compound, an alkoxy methane compound, and an organic thio compound. The composition provided by the present invention has stable performance, and can be used as a fire extinguishing agent, a heat transfer medium, etc.

  本发明公开了一种组合物，该组合物包含：(A) 至少一种含氟酮；(B) 有效量的稳定剂，该稳定剂选自环氧化合物、硝基化合物、受阻酚类化合物、β-二酮化合物、亚磷酸酯化合物、水杨酸盐化合物、肉桂酸盐化合物、羟基二苯甲酮化合物、羟基苯甲酸化合物、烷氧基甲烷化合物和有机硫化合物中的至少一种。本发明提供的组合物性能稳定，可用作灭火剂、传热介质等。
• Synthesis of polyfluoroalkylated 1,4-diazinols and 1,4-oxazinols using polyfluoro-2,3-epoxyalkanes32 + 13
  作者：L.V. Saloutina、A.Ya. Zapevalov、M.I. Kodess、V.I. Saloutin

  DOI：10.1016/s0022-1139(97)00102-4

  日期：1998.1

  It has been found that the reactions of polyfluoro-2,3-epoxyalkanes with ethylenediamine and 2-aminoethanol yield 2,3-di(polyfluoroalkyl)- 1,5,6-trihydro-1,4-diazin-2-ols and 2,3-di(polyfluoroalkyl)-5,6-dihydro-1,4-oxazin-2-ols, respectively. In the case of unsymmetrical oxiranes mixtures of regioisomeric heterocyclic compounds have been obtained. These reactions were found to give some by products-N,N'-bis(polyfluoroacyl) ethylenediamines and N-polyfluoroacyl-2-aminoethanols. (C) 1998 Elsevier Science S.A.
• Saloutina, L. V.; Zapevalov, A. Ya., Russian Journal of Organic Chemistry, 1993, vol. 29, # 7.1, p. 1108 - 1117
  作者：Saloutina, L. V.、Zapevalov, A. Ya.

  DOI：——

  日期：——
• COMPOSITION COMPRISING FLUORINE-CONTAINING KETONE
  申请人：Sinochem Lantian Co., Ltd

  公开号：US20180200553A1

  公开（公告）日：2018-07-19

  Disclosed is a composition comprising: (A) at least one fluorine-containing ketone; and (B) an effective amount of stabilizer which is selected from at least one of the group consisting of an epoxy compound, a nitro compound, a hindered phenolic compound, a β-diketone compound, a phosphite compound, a salicylate compound, a cinnamate compound, a hydroxybenzophenone compound, a hydroxybenzoic acid compound, an alkoxy methane compound, and an organic thio compound, The composition provided by the present invention has stable performance, and can be used as a fire extinguishing agent, a heat transfer medium, etc.