1-(1,1-dimethyl-5-hexen-2-ynyloxy)-2,3-epoxypropane | 75143-40-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(1,1-dimethyl-5-hexen-2-ynyloxy)-2,3-epoxypropane
• 英文别名: glycidyl ether of allylethynyldimethylcarbinol；1-(1,1-Dimethyl-5-hexen-2-ynyloxy)-2,3-epoxy-propane；2-(2-methylhept-6-en-3-yn-2-yloxymethyl)oxirane
• CAS: 75143-40-7
• 化学式: C₁₁H₁₆O₂
• 分子量: 180.247
• InChiKey: WCTIFTMSRAPNJF-UHFFFAOYSA-N

物化性质

• 沸点：
  254.1±20.0 °C(Predicted)
• 密度：
  0.989±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(1,1-dimethyl-5-hexen-2-ynyloxy)-2,3-epoxypropane 、 丙酮 在 三氟化硼乙醚 作用下， 以76.1%的产率得到
  参考文献：
  名称：

  Allylacetylenes and their derivatives as inhibitors of steel corrosion in sulfuric acid

  摘要：

  New functionalized derivatives of allylacetylenes were prepared, and their ability to inhibit corrosion of St.3 low-carbon steel in 5 N sulfuric acid was studied. The effectiveness of inhibition of steel corrosion was studied in relation to the structure of acetylene derivatives, their concentration, and temperature of acidic medium.

  DOI：

  10.1134/s1070427206110176
• 作为产物：
  描述：

  2-甲基-3-丁炔-2-醇 在 氢氧化钾 、 copper(l) iodide 、 三氟化硼乙醚 、 potassium carbonate 、 三乙胺 作用下， 以 乙醚 、 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 生成 1-(1,1-dimethyl-5-hexen-2-ynyloxy)-2,3-epoxypropane
  参考文献：
  名称：

  Allylacetylenes and their derivatives as inhibitors of steel corrosion in sulfuric acid

  摘要：

  New functionalized derivatives of allylacetylenes were prepared, and their ability to inhibit corrosion of St.3 low-carbon steel in 5 N sulfuric acid was studied. The effectiveness of inhibition of steel corrosion was studied in relation to the structure of acetylene derivatives, their concentration, and temperature of acidic medium.

  DOI：

  10.1134/s1070427206110176

文献信息

• Diene condensation of allylacetylene and some of its derivatives with polychlorocyclic dienes
  作者：M. G. Veliev、M. M. Guseinov、L. A. Yanovskaya、�. Sh. Mamedov、A. A. Bairamov

  DOI：10.1007/bf00958820

  日期：1980.6
• Veliev, M. G.; Chalabieva, A. Z.; Gakhramanov, R. F., Russian Journal of Organic Chemistry, 1994, vol. 30, # 1.1, p. 42 - 48
  作者：Veliev, M. G.、Chalabieva, A. Z.、Gakhramanov, R. F.、Mustafaev, A. M.

  DOI：——

  日期：——
• Diene Condensation of Cyclopentadiene with Dienophiles of Allylacetylene Series
  作者：M. G. Veliev、A. Z. Chalabieva、M. I. Shatirova、E. G. Akperova

  DOI：10.1023/b:rujo.0000003159.15212.50

  日期：2003.6

  Diene condensation of cyclopentadiene with 2-substituted allylacetylenes occurs nonselectively at a double and triple bonds; therewith the dienophile activity grows in parallel with the electron-withdrawing properties of the substituent. Depending on electronic character of functional groups the reaction proceeds as ''neutral" diene synthesis. The relative activity of cyclopentadiene and 1,3-cyclohexadiene in reactions with allylacetylenes is essentially governed by the different distance between the 1,4-reactive sites in these systems.
• VELIEV M. G.; GUSEJNOV M. M.; YANOVSKAYA L. A.; MAMEDOV EH. SH.; BAJRAMOV+, IZV. AN CCCP. CEP. XIM., 1980, HO 6, 1358-1362
  作者：VELIEV M. G.、 GUSEJNOV M. M.、 YANOVSKAYA L. A.、 MAMEDOV EH. SH.、 BAJRAMOV+

  DOI：——

  日期：——