bis(3-allylsalicylidene-2'-mercaptoanilinato)dicopper(II) | 1450751-02-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(3-allylsalicylidene-2'-mercaptoanilinato)dicopper(II)
• 英文别名: bis(3-allylsalicylal-2'-mercaptoanilinato)dicopper(II)
• CAS: 1450751-02-6
• 化学式: C₃₂H₂₆Cu₂N₂O₂S₂
• 分子量: 661.795
• InChiKey: IPBOLYMFGPTEMC-CQGBIQBTSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 acetate monohydrate 作用下， 以 甲醇 为溶剂， 反应 2.0h， 生成 bis(3-allylsalicylidene-2'-mercaptoanilinato)dicopper(II)
  参考文献：
  名称：

  Synthesis, X-ray spectral, and magnetochemical study of copper complexes based on tridentate azomethines of 3-allylsalicylaldehyde

  摘要：

  Tridentate azomethine ligands (H2L) based on 3-allylsalicylaldehyde and o-aminophenol, o-aminothiophenol, or 2-ethylamino-5-nitroaniline were synthesized and identified by IR and H-1 NMR spectroscopies. The structure of complexes (Ia-Ic) was studied by magnetochemistry and EXAFS spectroscopy. Complexes Ia and Ib (X = O, S) are binuclear and exhibit antiferromagnetic exchange interaction: 2J = -36.5 and -950 cm(-1), respectively. Complex Ic (X = NC2H5) is mononuclear (mu(eff) = 1.75 mu(B) at 275 K and does not change as temperature decreases).

  DOI：

  10.1134/s1070328413040039

文献信息

• Synthesis and reactivity of metal-containing monomers
  作者：B. A. Komarov、A. T. Kapasharov、E. A. Dzhavadyan、V. A. Lesnichaya、G. I. Dzhardimalieva、A. S. Burlov、A. I. Uraev、S. A. Mashchenko、D. A. Garnovskii、A. D. Pomogailo

  DOI：10.1007/s11172-015-0958-7

  日期：2015.4

  of additives of copper azomethine complexes of different structure on the character of polycondensation and physicomechanical properties of the obtained metal-containing epoxy polymers was studied. It was shown by the DSC method that the thermal stability of the starting CuII azomethine complexes depended on their structure and nature of polar functional groups. The physicomechanical properties of

  研究了不同结构的偶氮甲碱铜配合物的添加剂对所得含金属环氧聚合物的缩聚特性和物理机械性能的影响。DSC 方法表明，起始 CuII 偶氮甲碱配合物的热稳定性取决于它们的结构和极性官能团的性质。比较了不同官能团比例下未改性和改性环氧胺聚合物的物理机械性能。研究表明，0.42-0.43 wt.% 的 CuII 偶氮甲碱配合物添加剂可在 [NH]/EG = 1.07-1.13（EG 是环氧基团）的比率下提高聚合物的冲击强度。