Me2GeT(1+) | 1243627-28-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Me2GeT(1+)
• CAS: 1243627-28-2
• 化学式: C₂H₇Ge
• 分子量: 105.66
• InChiKey: ZEJUMEYTQOVJPE-WJULDGBESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.52
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  甲基叔丁基醚 、 Me2GeT(1+) 以 gas 为溶剂， 以74%的产率得到methoxydimethylgermane-t
  参考文献：
  名称：

  A radiochemical study of isomerization of dimethylgermylium ion, with the reaction of Me2HGe+ cation with methyl tert-butyl ether as example

  摘要：

  The reaction of dimethylgermylium ion with methyl tert-butyl ether in the gas phase was studied by the radiochemical method, and the mechanisms of the corresponding ion-molecule reactions were suggested. The possibility of the existence of germylium ions generated by the nuclear-chemical method was proved by the example of dimethylgermylium ion. Possible pathways of transformation of (CH3)(2)HGe+ cation into other isomeric forms were analyzed by B3LYP calculations with 6-31G* and aug-cc-pVDZ basis sets.

  DOI：

  10.1134/s1066362210010224
• 作为产物：
  描述：

  dimethylditritiogermane 以 not given 为溶剂， 生成 Me2GeT(1+)
  参考文献：
  名称：

  Gas phase reaction of nucleogenic dimethylgermylium cations with benzene

  摘要：

  Reaction of nucleogenic dimethylgermylium cations with benzene in the gas phase was studied by the radiochemical method. The formation of the products of germylation of benzene, dimethylphenylgermane, and phenylgermane is indicative of the formation of dimethylgermylium cations by the beta-decay of tritium in the molecule of dimethylditritium germane. Dimethylgermylium cations are shown to undergo a rearrangement in the course of the reaction with benzene, which is consistent with the earlier results of quantum-chemical calculations.

  DOI：

  10.1134/s1070363210090070