Methanesulfonic acid (S)-1-azidomethyl-2-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylethynyl)-tetrahydro-pyran-2-yl]-ethyl ester | 178388-15-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Methanesulfonic acid (S)-1-azidomethyl-2-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylethynyl)-tetrahydro-pyran-2-yl]-ethyl ester
• CAS: 178388-15-3
• 化学式: C₆₇H₇₁N₃O₁₃S
• 分子量: 1158.38
• InChiKey: FCVZXNCGACYXJM-UMPUZUFSSA-N

反应信息

• 作为反应物：
  描述：

  Methanesulfonic acid (S)-1-azidomethyl-2-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylethynyl)-tetrahydro-pyran-2-yl]-ethyl ester 以100%的产率得到methyl (5R)-5-C-{[2R-(2α(6'S*),3α,4β,5α,6β)]-3,4,5-tribenzyloxy-6-benzyloxy-methyl-3,4,5,6,6',7'-hexahydro-6'-(methanesulfonyloxy)spiro[2H-pyran-2,4'(5'H)-[1,2,3]-triazolo[1,5-a]pyridine]3'-yl}-2,3,4-tri-O-benzyl-α-D-xylopyranoside
  参考文献：
  名称：

  Streicher, Hansjoerg; Geyer, Armin; Schmidt, Richard R., Chemistry - A European Journal, 1996, vol. 2, # 5, p. 502 - 510

  摘要：

  DOI：
• 作为产物：
  描述：

  Methanesulfonic acid (S)-1-methanesulfonyloxymethyl-2-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylethynyl)-tetrahydro-pyran-2-yl]-ethyl ester 在 sodium azide 、 15-冠醚-5 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以5%的产率得到methyl (5R)-5-C-{[2R-(2α(6'S*),3α,4β,5α,6β)]-3,4,5-tribenzyloxy-6-benzyloxy-methyl-3,4,5,6,6',7'-hexahydro-6'-(methanesulfonyloxy)spiro[2H-pyran-2,4'(5'H)-[1,2,3]-triazolo[1,5-a]pyridine]3'-yl}-2,3,4-tri-O-benzyl-α-D-xylopyranoside
  参考文献：
  名称：

  Streicher, Hansjoerg; Geyer, Armin; Schmidt, Richard R., Chemistry - A European Journal, 1996, vol. 2, # 5, p. 502 - 510

  摘要：

  DOI：