3-(but-3-enyl)-tricyclo[6.2.0.0^2,6]dec-2,9-diene | 1407188-37-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 3-(but-3-enyl)-tricyclo[6.2.0.0^2,6]dec-2,9-diene
• 英文别名: 10-But-3-enyltricyclo[5.3.0.02,5]deca-1(10),3-diene；10-but-3-enyltricyclo[5.3.0.02,5]deca-1(10),3-diene
• CAS: 1407188-37-7
• 化学式: C₁₄H₁₈
• 分子量: 186.297
• InChiKey: OBQCQNCZZSWYDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  5-(2-methoxyphenyl)-nona-1,8-dien-5-ol 以 环己烷 为溶剂， 反应 72.0h， 以1%的产率得到9-(but-3-enyl)-bicyclo[6.3.0^1,8]undec-4,6,8-triene-3-one
  参考文献：
  名称：

  Investigating the Photochemical Properties of an Arenyl Dienol

  摘要：

  Upon irradiation with UV light, an arenyl dienol was transformed into linear and angular meta photocycloadducts and ortho derived photoadducts. Extended exposure to UV radiation resulted in the formation of other degradation products, which shed light on the chemical processes taking place. One of the linear meta photocycloadducts was thermally unstable and underwent further thermal and photochemical transformation, while the ortho-derived photocycloadducts ring-opened and eliminated methanol to afford a cyclooctadienone product.

  DOI：

  10.1021/ol302718p

文献信息

• Investigating the Photochemical Properties of an Arenyl Dienol
  作者：Clive S. Penkett、Jason A. Woolford

  DOI：10.1021/ol302718p

  日期：2012.11.16

  Upon irradiation with UV light, an arenyl dienol was transformed into linear and angular meta photocycloadducts and ortho derived photoadducts. Extended exposure to UV radiation resulted in the formation of other degradation products, which shed light on the chemical processes taking place. One of the linear meta photocycloadducts was thermally unstable and underwent further thermal and photochemical transformation, while the ortho-derived photocycloadducts ring-opened and eliminated methanol to afford a cyclooctadienone product.