(4-(diphenylamino)-6-phenyl-1,3,5-triazin-2-yl)(phenyl)methanone | 1256170-24-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (4-(diphenylamino)-6-phenyl-1,3,5-triazin-2-yl)(phenyl)methanone
• 英文别名: phenyl-[4-phenyl-6-(N-phenylanilino)-1,3,5-triazin-2-yl]methanone
• CAS: 1256170-24-7
• 化学式: C₂₈H₂₀N₄O
• 分子量: 428.493
• InChiKey: FJGBJKCSMJOYPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  59
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  4-iodo-N,N,6-triphenyl-1,3,5-triazin-2-amine 、 苯甲酰氯 在 正丁基氯化镁 、 copper(I) cyanide di(lithium chloride) 作用下， 以 四氢呋喃 为溶剂， 反应 12.34h， 以71%的产率得到(4-(diphenylamino)-6-phenyl-1,3,5-triazin-2-yl)(phenyl)methanone
  参考文献：
  名称：

  Preparation of 2-Magnesiated 1,3,5-Triazines via an Iodine−Magnesium Exchange

  摘要：

  Functionalized iodo- and diiodo-1,3,5-triazine derivatives readily undergo an I/Mg exchange with BuMgCl, sBuMgCl, or OctMgBr at low temperatures. furnishing 2-magnesiated and 2-zincated 1,3,5-triazines (after transmetalation with ZnCl2). This method also offers a convenient access to dimagnesiated triazines. Furthermore, it allows the preparation of functionalized 1,3,5-triazinyl dimers and trimers, interesting for their optoelectronic properties.

  DOI：

  10.1021/ol102173z

文献信息

• Preparation of 2-Magnesiated 1,3,5-Triazines via an Iodine−Magnesium Exchange
  作者：Zhihua Peng、Benjamin A. Haag、Paul Knochel

  DOI：10.1021/ol102173z

  日期：2010.12.3

  Functionalized iodo- and diiodo-1,3,5-triazine derivatives readily undergo an I/Mg exchange with BuMgCl, sBuMgCl, or OctMgBr at low temperatures. furnishing 2-magnesiated and 2-zincated 1,3,5-triazines (after transmetalation with ZnCl2). This method also offers a convenient access to dimagnesiated triazines. Furthermore, it allows the preparation of functionalized 1,3,5-triazinyl dimers and trimers, interesting for their optoelectronic properties.