4-methoxybenzyl 2,3,6-tri-O-benzoyl-β-D-glucopyranoside | 1017592-53-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-methoxybenzyl 2,3,6-tri-O-benzoyl-β-D-glucopyranoside
• 英文别名: [(2R,3R,4S,5R,6R)-4,5-dibenzoyloxy-3-hydroxy-6-[(4-methoxyphenyl)methoxy]oxan-2-yl]methyl benzoate
• CAS: 1017592-53-8
• 化学式: C₃₅H₃₂O₁₀
• 分子量: 612.633
• InChiKey: XIHMLJMZJAZFHI-DUCQPWDXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  45
• 可旋转键数：
  14
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  127
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  2-deoxy-1-thioglycoside 、 4-methoxybenzyl 2,3,6-tri-O-benzoyl-β-D-glucopyranoside 在 N-碘代丁二酰亚胺 、 三氟甲磺酸 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以55%的产率得到
  参考文献：
  名称：

  Synthesis of 2-deoxy-d-arabino/lyxo-hexopyranosyl disaccharides

  摘要：

  Synthesis of 2-deoxy-D-arabino/lyxo-hexopyranosyl disaccharides is reported. In these, the disaccharides contain 2-deoxy-arabino-hexopyranosyl and 2-deoxy-lyxo-hexopyranosyl sugars as either the reducing or the non-reducing or both the sugar units of the disaccharides. The activated 2-deoxy-1-thioglycosides served as the common precursors to prepare the 2-deoxy disaccharides with the above configurations. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2007.11.017
• 作为产物：
  描述：

  4-methoxybenzyl 2,3-di-O-benzoyl-β-D-glucopyranoside 、 苯甲酰氯 在 ⁿBu₂SnO 作用下， 以 甲苯 为溶剂， 反应 0.08h， 以93%的产率得到4-methoxybenzyl 2,3,6-tri-O-benzoyl-β-D-glucopyranoside
  参考文献：
  名称：

  Synthesis of 2-deoxy-d-arabino/lyxo-hexopyranosyl disaccharides

  摘要：

  Synthesis of 2-deoxy-D-arabino/lyxo-hexopyranosyl disaccharides is reported. In these, the disaccharides contain 2-deoxy-arabino-hexopyranosyl and 2-deoxy-lyxo-hexopyranosyl sugars as either the reducing or the non-reducing or both the sugar units of the disaccharides. The activated 2-deoxy-1-thioglycosides served as the common precursors to prepare the 2-deoxy disaccharides with the above configurations. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2007.11.017

文献信息

• Synthesis of 2-deoxy-d-arabino/lyxo-hexopyranosyl disaccharides
  作者：Somak Paul、Narayanaswamy Jayaraman

  DOI：10.1016/j.carres.2007.11.017

  日期：2008.2

  Synthesis of 2-deoxy-D-arabino/lyxo-hexopyranosyl disaccharides is reported. In these, the disaccharides contain 2-deoxy-arabino-hexopyranosyl and 2-deoxy-lyxo-hexopyranosyl sugars as either the reducing or the non-reducing or both the sugar units of the disaccharides. The activated 2-deoxy-1-thioglycosides served as the common precursors to prepare the 2-deoxy disaccharides with the above configurations. (c) 2007 Elsevier Ltd. All rights reserved.