2,2,3-Trimethyl-1-(4-trifluoromethyl-phenyl)-3-[3-(4-trifluoromethyl-phenyl)-dithiiran-3-yl]-butan-1-one | 167321-43-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2,3-Trimethyl-1-(4-trifluoromethyl-phenyl)-3-[3-(4-trifluoromethyl-phenyl)-dithiiran-3-yl]-butan-1-one
• CAS: 167321-43-9
• 化学式: C₂₂H₂₀F₆OS₂
• 分子量: 478.523
• InChiKey: MZTSLQQVCVWOCN-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2,2,3-Trimethyl-1-(4-trifluoromethyl-phenyl)-3-[3-(4-trifluoromethyl-phenyl)-dithiiran-3-yl]-butan-1-one 在 MeN⁽¹⁺⁾(C₈H₁₇)3Cl^(1-) 三乙胺 作用下， 以 二氯甲烷 、 水 为溶剂， 生成 2,2,3,3-Tetramethyl-4-thioxo-1,4-bis-(4-trifluoromethyl-phenyl)-butan-1-one
  参考文献：
  名称：

  Reaction of 1,3-dithietanes with 2KHSO5·KHSO4·K2SO4: Scope and limitation for the preparation of dithiirane derivatives

  摘要：

  The reaction of 5,6-dithiabicyclo[2.1.1]hexane derivatives with OXONE in a two-phase mixture of dichloromethane and water gave the corresponding dithiirane derivatives which were stable in solution. The formation of the dithiiranes were proved by UV-Vis spectra and chemical transformations. The reaction of 7,8-dithiabicyclo[4.1.1]octane derivatives with OXONE gave the corresponding cis-dithiirane oxides. The reaction of the head-to-tail dimer of 2-adamantanethione with OXONE gave 2-adamantanone as the sole detectable material.

  DOI：

  10.1016/0040-4039(95)00136-z
• 作为产物：
  描述：

  2,2,3,3-Tetramethyl-1,4-bis-(4-trifluoromethyl-phenyl)-5,6-dithia-bicyclo[2.1.1]hexane 在 MeN⁽¹⁺⁾(C₈H₁₇)3Cl^(1-) 氢氧化钾 、 potassium sulfate 、 potassium hydrogensulfate 、 oxone 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 24.0h， 以19%的产率得到2,2,3-Trimethyl-1-(4-trifluoromethyl-phenyl)-3-[3-(4-trifluoromethyl-phenyl)-dithiiran-3-yl]-butan-1-one
  参考文献：
  名称：

  Reaction of 1,3-dithietanes with 2KHSO5·KHSO4·K2SO4: Scope and limitation for the preparation of dithiirane derivatives

  摘要：

  The reaction of 5,6-dithiabicyclo[2.1.1]hexane derivatives with OXONE in a two-phase mixture of dichloromethane and water gave the corresponding dithiirane derivatives which were stable in solution. The formation of the dithiiranes were proved by UV-Vis spectra and chemical transformations. The reaction of 7,8-dithiabicyclo[4.1.1]octane derivatives with OXONE gave the corresponding cis-dithiirane oxides. The reaction of the head-to-tail dimer of 2-adamantanethione with OXONE gave 2-adamantanone as the sole detectable material.

  DOI：

  10.1016/0040-4039(95)00136-z