| 194655-30-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 194655-30-6
• 化学式: C₄₃H₆₃N₃O₂₂
• 分子量: 973.98
• InChiKey: KRNPPXUSKVBGBJ-IOJBAASYSA-N

反应信息

• 作为反应物：
  描述：

  Phosphoric acid (2R,3S,4R,5R)-5-(2-amino-6-oxo-1,6-dihydro-purin-9-yl)-3,4-dihydroxy-tetrahydro-furan-2-ylmethyl ester (3S,4R,5S,6S)-3,4,5-trihydroxy-6-methyl-tetrahydro-pyran-2-yl ester 、 在 bovine serum albumine 、 calf intestine alkaline phosphatase 、 fucosyl transferase-III 、 Na-cacodylate buffer 、 manganese(ll) chloride 作用下， 以 水 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  Enzymatic fucosylations of non-natural sialylated type-I trisaccharides with recombinant fucosyl-transferase-III

  摘要：

  Recombinant fucosyl-transferase-III (Lewis type enzyme) is used to prepare a series of non-natural sialyl-Lewis(a) derivatives on a preparative scale. The enzyme tolerates a wide range of accepters which have the natural N-acetyl group of the glucosamine moiety replaced by substituted aromatic and heteroaromatic amides. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0960-894x(97)10202-5
• 作为产物：
  描述：

  9-[(2R,3R,4R,5S,6R)-5-Acetoxy-6-acetoxymethyl-3-[(8-hydroxy-quinoline-2-carbonyl)-amino]-4-((2R,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-nonanoic acid methyl ester 在 bovine serum albumine 、 α(2-3)-(N)-sialyltransferase 、 calf intestine alkaline phosphatase 、 Na-cacodylate buffer 、 sodium methylate 、 manganese(ll) chloride 作用下， 以 甲醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Enzymatic α(2–3)sialylation of non-natural type-I (Lewisc) disaccharides with recombinant sialyl-transferase

  摘要：

  Recombinant alpha(2-3)sialyl-transferase from rat liver is used to sialylate a series of type-I (Lewis(c)) disaccharides on a preparative scale. The enzyme tolerates a broad array of N-acetyl replacements of the N-glucosamine subunit ranging from small and large lipophilic groups to charged and heterocyclic amides. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0960-894x(97)10201-3