(E)-CH(t-Bu)=CH(2-(CH2NMe2)C6H4) | 267899-05-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-CH(t-Bu)=CH(2-(CH2NMe2)C6H4)
• CAS: 267899-05-8
• 化学式: C₁₅H₂₃N
• 分子量: 217.354
• InChiKey: ZMMYIQPJFCGASI-ZHACJKMWSA-N

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 3,3-二甲基-1-丁炔 、 [(η(5)-C5H5)Co(4-C6H4CH2NMe2-C(2),N)I] 以 二氯甲烷 为溶剂， 以38%的产率得到[(η(5)-C5H5)Co[η(5)-C5H4CH=C(t-Bu)(2-(CH2NMe2)C6H4)]]PF6
  参考文献：
  名称：

  Reactivity of Cyclocobaltated Benzylamine Derivatives toward Terminal Alkynes

  摘要：

  The cyclocobaltated complexes [(eta(5)-C5H5)Co(4-RC6H3CH2NMe2-C-2,N)I] (1; R = H, Me, F) reacted with terminal alkynes such as R'C=CH (2; R' = Bu-t, SiMe3) to afford a mixture of the two compounds {(eta(5)-C5H5)Co[eta(5)-C5H4CH=CR'(4-R-2-(CH2NMe2)C6H3)]}+PF6- (3) and(E)-CHR'=CH(4-R-2-(CH2NMe2)C6H3) (4) in a ca. 1:1 ratio. The reaction is rationalized by assuming that insertion of the alkyne into the Co-C bond of 1 occurred with no regioselectivity, leading to two unstable regioisomers; a selective migration of the less hindered allrenyl-Co derivative to a Cp unit followed by migration, of the monosubstituted Cp ring thus obtained to another cobalt center afforded 3, whereas compound 4 should be obtained via protiodemetalation of the other isomer formed.

  DOI：

  10.1021/om000053p