tris(4-(6-(9H-carbazol-9-yl)-4-phenylquinolin-2-yl)phenyl)amine | 1544752-82-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: tris(4-(6-(9H-carbazol-9-yl)-4-phenylquinolin-2-yl)phenyl)amine
• 英文别名: 4-(6-carbazol-9-yl-4-phenylquinolin-2-yl)-N,N-bis[4-(6-carbazol-9-yl-4-phenylquinolin-2-yl)phenyl]aniline
• CAS: 1544752-82-0
• 化学式: C₉₉H₆₃N₇
• 分子量: 1350.64
• InChiKey: GHZGWGAQRXYTLG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.1
• 重原子数：
  106
• 可旋转键数：
  12
• 环数：
  21.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (2-amino-5-(9H-carbazol-9-yl)phenyl)(phenyl)methanone 、 tris(4-acetylphenyl)amine 在 四磷十氧化物 作用下， 反应 12.0h， 以60%的产率得到tris(4-(6-(9H-carbazol-9-yl)-4-phenylquinolin-2-yl)phenyl)amine
  参考文献：
  名称：

  Molecular design for the highly-sensitive piezochromic fluorophores with tri-armed framework containing triphenyl-quinoline moiety

  摘要：

  Two tri-armed piezochromic fluorescent molecules of tris(4-(4-phenylquinolin-2-yl)phenyl)amine (TPA-3Qu) and tris(4-(6-(9H-carbazol-9-yl)-4-phenylquinolin-2-yl)phenyl)amine (TPA-3QuCz) were prepared and found to exhibit keen fluorescence responses toward compression. With the framework of a twisted, pyramidal triphenylamine (TPA) center connecting to three large quinolinecarbazole (QuCz) arms, the amorphous TPA-3QuCz exhibited a large bathochromic shift of 112 nm under gentle grinding forces, which is different from the small shift of 32 nm for TPA-3Qu under applying a relatively-large pressure of 10 MPa. Conformational transformations involving planarization of the arms were proposed to account for the observed fluorescence responses of TPA-3QuCz and TPA-3Qu towards pressure. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.11.016

文献信息

• Molecular design for the highly-sensitive piezochromic fluorophores with tri-armed framework containing triphenyl-quinoline moiety
  作者：Tai-Shen Hsiao、Tai-Lin Chen、Wei-Lun Chien、Jin-Long Hong

  DOI：10.1016/j.dyepig.2013.11.016

  日期：2014.4

  Two tri-armed piezochromic fluorescent molecules of tris(4-(4-phenylquinolin-2-yl)phenyl)amine (TPA-3Qu) and tris(4-(6-(9H-carbazol-9-yl)-4-phenylquinolin-2-yl)phenyl)amine (TPA-3QuCz) were prepared and found to exhibit keen fluorescence responses toward compression. With the framework of a twisted, pyramidal triphenylamine (TPA) center connecting to three large quinolinecarbazole (QuCz) arms, the amorphous TPA-3QuCz exhibited a large bathochromic shift of 112 nm under gentle grinding forces, which is different from the small shift of 32 nm for TPA-3Qu under applying a relatively-large pressure of 10 MPa. Conformational transformations involving planarization of the arms were proposed to account for the observed fluorescence responses of TPA-3QuCz and TPA-3Qu towards pressure. (C) 2013 Elsevier Ltd. All rights reserved.