6,14-didecyl-6,14-dihydrobenzo[b]benzo[5,6]indolo[2,3-h]carbazole | 1595126-42-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 6,14-didecyl-6,14-dihydrobenzo[b]benzo[5,6]indolo[2,3-h]carbazole
• 英文别名: 14,28-Didecyl-14,28-diazaheptacyclo[15.11.0.03,15.04,13.06,11.018,27.020,25]octacosa-1(17),2,4,6,8,10,12,15,18,20,22,24,26-tridecaene；14,28-didecyl-14,28-diazaheptacyclo[15.11.0.03,15.04,13.06,11.018,27.020,25]octacosa-1(17),2,4,6,8,10,12,15,18,20,22,24,26-tridecaene
• CAS: 1595126-42-3
• 化学式: C₄₆H₅₆N₂
• 分子量: 636.964
• InChiKey: FRJYXORUQWTGAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.5
• 重原子数：
  48
• 可旋转键数：
  18
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3,7-bis(2-(bromomethyl)benzyl)-1,5-didecyl-3,7-bis((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)thio)-5,7-dihydropyrrolo[2,3-f]indole-2,6(1H,3H)-dione 在 samarium diiodide 、 六氟异丙醇 、 对苯醌 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 2.03h， 生成 6,14-didecyl-6,14-dihydrobenzo[b]benzo[5,6]indolo[2,3-h]carbazole 、 二(1H,1H,2H,2H-全氟癸基)二硫醚
  参考文献：
  名称：

  A Sm(II)-Mediated Cascade Approach to Dibenzoindolo[3,2-b]carbazoles: Synthesis and Evaluation

  摘要：

  Previously unstudied dibenzoindolo[3,2-b]carbazoles have been prepared by two-directional, phase tag-assisted synthesis utilizing a connective-Pummerer cyclization and a SmI2-mediated tag cleavage-cyclization cascade. The use of a phase tag allows us to exploit unstable intermediates that would otherwise need to be avoided. The novel materials were characterized by X-ray, cyclic voltammetry, UV-vis spectroscopy, TGA, and DSC. Preliminary studies on the performance of OFET devices are also described.

  DOI：

  10.1021/ol500841b

文献信息

• A Sm(II)-Mediated Cascade Approach to Dibenzoindolo[3,2-<i>b</i>]carbazoles: Synthesis and Evaluation
  作者：Matthew T. Levick、Iain Grace、Sheng-Yao Dai、Nicholas Kasch、Christopher Muryn、Colin Lambert、Michael L. Turner、David J. Procter

  DOI：10.1021/ol500841b

  日期：2014.4.18

  Previously unstudied dibenzoindolo[3,2-b]carbazoles have been prepared by two-directional, phase tag-assisted synthesis utilizing a connective-Pummerer cyclization and a SmI2-mediated tag cleavage-cyclization cascade. The use of a phase tag allows us to exploit unstable intermediates that would otherwise need to be avoided. The novel materials were characterized by X-ray, cyclic voltammetry, UV-vis spectroscopy, TGA, and DSC. Preliminary studies on the performance of OFET devices are also described.