2-methyltridecanal | 17110-09-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-methyltridecanal
• 英文别名: 2-methyl-1-tridecanal
• CAS: 17110-09-7
• 化学式: C₁₄H₂₈O
• 分子量: 212.376
• InChiKey: BBBHELVSOCQEHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-methyltridecanal 生成 2-methyltridecan-1-ol
  参考文献：
  名称：

  OSWALD, ALEXIS A.;BHATIA, RAM N.

  摘要：

  DOI：
• 作为产物：
  描述：

  1-十三烯 生成 2-methyltridecanal
  参考文献：
  名称：

  OSWALD, ALEXIS A.;BHATIA, RAM N.

  摘要：

  DOI：

文献信息

• Rhodium‐Catalyzed Formylation of Unactivated Alkyl Chlorides to Aldehydes
  作者：Peng Wang、Yaxin Wang、Helfried Neumann、Matthias Beller

  DOI：10.1002/chem.202203342

  日期：2023.2.7

  An efficient and convenient rhodium-catalyzed formylation of alkyl chlorides to synthesize aldehydes has been developed. Depending on the conditions both linear and branched aldehydes can be obtained in a selective manner from readily available substrates.

  已开发出一种有效且方便的铑催化的烷基氯甲酰化合成醛。根据条件，直链和支链醛都可以以选择性的方式从容易获得的底物中获得。
• Process for catalyst-aldehyde product separation
  申请人：UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

  公开号：EP0350922A2

  公开（公告）日：1990-01-17

  Process for the separation and recovery of aldehyde product from a non-aqueous hydroformylation reaction product composition comprising the aldehyde product, a rhodium-ionically charged phosphorus ligand complex, a free ionically charged phosphorus ligand and an organic solubilizing agent for said complex and said free ligand via phase separation using added water or both added water and an added non-polar hydrocarbon compound.

  从非水加氢甲酰化反应产物组合物中分离和回收醛产物的工艺，该组合物包括醛产物、铑-带离子电荷的磷配位体络合物、游离的带离子电荷的磷配位体以及用于所述络合物和游离配位体的有机增溶剂，通过使用添加的水或添加的水和添加的非极性烃化合物进行相分离。
• Improved metal-ligand complex catalyzed processes
  申请人：UNION CARBIDE CHEMICALS & PLASTICS

  公开号：EP1108707A1

  公开（公告）日：2001-06-20

  This invention relates to a person for separating one or more phosphorus acidic compounds from a reaction product fluid containing said one or more phosphorus acidic compounds, a metal-organophosphite ligand complex catalyst and optionally free organophosphite ligand which process comprises (a) treating said reaction product fluid with water sufficient to remove at least some amount of said one or more phosphorus acidic compounds from said reaction product fluid and (b) treating the water which contains phosphorus acidic compounds removed from said reaction product fluid with an acid removal substance sufficient to remove at least some amount of said one or more phosphorus acidic compounds from said water.

  本发明涉及一种从含有一种或多种磷酸性化合物的反应产物流体中分离一种或多种磷酸性化合物的方法、本发明涉及一种从含有一种或多种磷酸性化合物的反应产物流体中分离出一种或多种磷酸性化合物的工艺，该工艺包括：(a) 用足以从反应产物流体中去除至少一定量的所述一种或多种磷酸性化合物的水处理所述反应产物流体；(b) 用足以从所述水中去除至少一定量的所述一种或多种磷酸性化合物的脱酸物质处理从所述反应产物流体中去除的含有磷酸性化合物的水。
• Hydroformylation process
  申请人：Dow Technology Investments LLC

  公开号：US10981851B2

  公开（公告）日：2021-04-20

  Some embodiments of the present invention relate to processes for reducing heavies formation in a solution comprising one or more aldehydes, such as a reaction fluid in a hydroformylation process. In some embodiments, the process comprises providing 0.1 to 5 wt. percent of an organic nitrogen compound based on the total weight of the aldehyde solution, the organic nitrogen compound comprising: wherein each of R1-R5 are independently hydrogen, an alkyl, or an aryl radical.

  本发明的一些实施方案涉及在包含一种或多种醛的溶液（如加氢甲酰化过程中的反应液）中减少重物形成的工艺。在一些实施方案中，该工艺包括提供基于醛溶液总重量 0.1 至 5 重量百分比的有机氮化合物，该有机氮化合物包括： 其中 R1-R5 中的每一个都独立地为氢、烷基或芳基。
• Processes for recovery of rhodium from a hydroformylation process
  申请人：Dow Technology Investments LLC

  公开号：US11033890B2

  公开（公告）日：2021-06-15

  Some embodiments of the present invention relate to processes to recover rhodium from a hydroformylation process. In some embodiments, the process to recover rhodium from the hydroformylation process comprises (a) treating a catalyst-containing stream from the hydroformylation process with 2.5 to 20 weight percent, based on the total weight of the stream, of a water-soluble organic amine of the following structure: wherein R32, R33, and R34 are each independently alkyls and ethoxylates, and wherein no more than one of R32, R33, and R34 is alkyl; (b) heating the resulting solution in the presence of syngas to a temperature of at least 65° C. to generate a rhodium-rich phase and a supernatant; and (c) removing the supernatant to recover the rhodium-rich phase.

  本发明的一些实施方案涉及从加氢甲酰化工艺中回收铑的工艺。在一些实施例中，从加氢甲酰化工艺中回收铑的工艺包括 (a) 用 2.其中 R32、R33 和 R34 各自独立地为烷基和乙氧基化物，且 R32、R33 和 R34 中不超过一个为烷基；(b) 在合成气存在下将所得溶液加热至至少 65°C 的温度，以生成富铑相和上清液；以及 (c) 去除上清液以回收富铑相。