2-methyltridecan-1-ol | 32480-16-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-methyltridecan-1-ol
• 英文别名: 2-Methyl-decanol；2-methyl-1-tridecanol；2-methyltridecanol
• CAS: 32480-16-3
• 化学式: C₁₄H₃₀O
• 分子量: 214.392
• InChiKey: YLQGFOSNRNDJDV-UHFFFAOYSA-N

物化性质

• 沸点：
  275.7±8.0 °C(Predicted)
• 密度：
  0.832±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-methyltridecan-1-ol 在 磷化氢 、 碘 作用下， 生成 (2-methyl-tridecyl)-malonic acid diethyl ester
  参考文献：
  名称：

  Weitzel; Wojahn, Hoppe-Seyler's Zeitschrift fur Physiologische Chemie, 1951, vol. 287, p. 65,88

  摘要：

  DOI：
• 作为产物：
  描述：

  1-溴十一烷 在 氢氧化钾 、 乙醇 、 硫酸 、 sodium 、 甲苯 作用下， 生成 2-methyltridecan-1-ol
  参考文献：
  名称：

  Weitzel; Wojahn, Hoppe-Seyler's Zeitschrift fur Physiologische Chemie, 1951, vol. 287, p. 65,88

  摘要：

  DOI：

文献信息

• [EN] BRANCHED ADIPIC ACID BASED ESTERS AS NOVEL BASE STOCKS AND LUBRICANTS<br/>[FR] ESTERS À BASE D'ACIDE ADIPIQUE RAMIFIÉ UTILISÉS EN TANT QUE NOUVELLES HUILES DE BASE ET LUBRIFIANTS
  申请人：BASF SE

  公开号：WO2019110355A1

  公开（公告）日：2019-06-13

  The presently claimed invention is directed to the use of branched adipic acid esters as lubricants as well as lubricant compositions containing the branched adipic acid esters.

  目前所声称的发明涉及使用分支脂肪族己二酸酯作为润滑剂，以及包含分支脂肪族己二酸酯的润滑剂组合物。
• Cyclometalated (NNC)Ru(<scp>ii</scp>) complex catalyzed β-methylation of alcohols using methanol
  作者：Kasturi Ganguli、Natalia V. Belkova、Sabuj Kundu

  DOI：10.1039/d1dt03967a

  日期：——

  this strategy, a wide range of primary, secondary, and aliphatic straight chain alcohols were selectively methylated. This protocol was further employed for the methylation of a few natural products and the gram scale synthesis of β-methylated alcohols. A series of control experiments and kinetic studies were performed to understand the plausible reaction mechanism.

  合成了含有基于菲咯啉的新配体及其相应的Ru( II )配合物的吲哚基片段，并通过各种光谱技术对其进行了充分表征。研究了这些新合成的环金属化 (NNC)Ru( II ) 配合物对使用甲醇对醇进行 β-甲基化的催化活性。值得注意的是，这些配合物与各种 (NNN)Ru( II) 配合物。利用这种策略，多种伯醇、仲醇和脂肪族直链醇被选择性甲基化。该协议进一步用于一些天然产物的甲基化和 β-甲基化醇的克级合成。进行了一系列对照实验和动力学研究，以了解合理的反应机制。
• Aqueous antioxidant emulsions
  申请人：Ciba-Geigy Corporation

  公开号：US05196142A1

  公开（公告）日：1993-03-23

  Storage-stable, non-sedimenting emulsions comprising a) 10 to 80% by weight, based on the emulsion, of one or more anti-oxidants, b) 0.25 to 10% by weight, based on the emulsion, of a surfactant in the form of a fatty acid salt of formula R-COOY, wherein R is straight chain or branched C.sub.3 -C.sub.18 alkyl or straight chain or branched C.sub.3 -C.sub.18 -alkenyl, or is phenyl(C.sub.3 -C.sub.18)alkyl, and Y is an alkali metal, which salt is prepared in situ from the fatty acid, c) 0.25 to 10% by weight, based on the emulsion, of a co-surfactant in the form of an alcohol of the general formula R'--OH, wherein R' is straight chain or branched C.sub.4 -C.sub.19 alkyl or straight chain or branched C.sub.4 -C.sub.19 alkenyl, or is phenyl(C.sub.4 -C.sub.19)alkyl, and d) water to make up 100%. The emulsions are used for stabilizing emulsion-polymerized polymers and copolymers such as ABS.

  存储稳定，不沉淀的乳液包括：a)占乳液重量的10-80％的一个或多个抗氧化剂；b)占乳液重量的0.25-10％的表面活性剂，其为公式R-COOY的脂肪酸盐的形式，其中R为直链或支链C.sub.3-C.sub.18烷基或直链或支链C.sub.3-C.sub.18烯基，或是苯基（C.sub.3-C.sub.18）烷基，而Y是碱金属，该盐是从脂肪酸原位制备的；c)占乳液重量的0.25-10％的共表面活性剂，其为一般公式R'-OH的醇的形式，其中R'为直链或支链C.sub.4-C.sub.19烷基或直链或支链C.sub.4-C.sub.19烯基，或是苯基（C.sub.4-C.sub.19）烷基；d)水，组成100％。该乳液用于稳定乳液聚合的聚合物和共聚物，例如ABS。
• Ethylene polymers with alpha-olefins
  申请人：SOCIETA' ITALIANA ADDITIVI PERCARBURANTI S.R.L.

  公开号：US20020002255A1

  公开（公告）日：2002-01-03

  Ethylene copolymers with octene and/or ethylene terpolymers with alpha-olefins from 3 to 12 carbon atoms, optionally in the presence of other comonomers containing more than one unsaturation, usable as additives to increase the gas oil properties at low temperatures, obtainable by polymerization of the monomers in the presence of catalysts comprising: a bis-cyclopentadienyl derivative having the general formula: (Cp 1 Cp 2 )—M—(L 2 L 3 ) containing groups with oxygen bound to the transition metal, wherein M is a metal from the IIIb group to the Vb group or of the lanthanide series of the Element Periodic Table; Cp 1 and CP 2 , equal to or different from each other, represent cyclopentadienyls bound to M with delocalized &pgr; bonds.

  含有辛烯和/或碳数为3到12的α-烯烃的乙烯共聚物或三元聚合物，可在其他含有多个不饱和度的共聚单体的存在下使用作为增加低温下气油性能的添加剂，制备方法是在催化剂的存在下聚合单体，所述催化剂包括具有以下一般式的双环戊二烯衍生物：(Cp1Cp2)-M-(L2L3)，其中含有氧原子与过渡金属结合，M是元素周期表IIIb至Vb族或镧系金属，Cp1和Cp2，相同或不同，代表与M结合的环戊二烯基，具有离域π键。
• Aqueous antioxident emulsions
  申请人：Ciba-Geigy Corporation

  公开号：US05059347A1

  公开（公告）日：1991-10-22

  Storage-stable, non-sedimenting emulsions comprising a) 10 to 80% by weight, based on the emulsion, of one or more antioxidants, b) 0.25 to 10% by weight, based on the emulsion, of a surfactant in the form of a fatty acid salt of formula R-COOY, wherein R is straight chain or branched C.sub.3 -C.sub.18 alkyl or straight chain or branched C.sub.3 -C.sub.18 -alkenyl, or is phenyl(C.sub.3 -C.sub.18)alkyl, and Y is an alkali metal, which salt is prepared in situ from the fatty acid, c) 0.25 to 10% by weight, based on the emulsion, of a co-surfactant in the form of an alcohol of the general formula R'--OH, wherein R' is straight chain or branched C.sub.4 -C.sub.19 alkyl or straight chain or branched C.sub.4 -C.sub.19 alkenyl, or is phenyl(C.sub.4 -C.sub.19)alkyl, and d) water to make up 100%. The emulsion are used for stabilizing emulsion-polymerized polymers and copolymers such as ABS.

  含有以下成分的储存稳定、不沉淀乳液：a) 单一或多种抗氧化剂，占乳液重量的10%至80%；b) 表面活性剂，占乳液重量的0.25%至10%，为式R-COOY的脂肪酸盐，其中R为直链或支链C.sub.3-C.sub.18烷基或直链或支链C.sub.3-C.sub.18烯基，或为苯基（C.sub.3-C.sub.18）烷基，Y为碱金属，该盐由脂肪酸原位制备；c) 合成辅助剂，占乳液重量的0.25%至10%，为一般式R'-OH的醇，其中R'为直链或支链C.sub.4-C.sub.19烷基或直链或支链C.sub.4-C.sub.19烯基，或为苯基（C.sub.4-C.sub.19）烷基；d) 水，占总重量为100%。该乳液用于稳定乳液聚合的聚合物和共聚物，如ABS。