9-chloro-1,4-acridinequinone | 1083096-00-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 9-chloro-1,4-acridinequinone
• 英文别名: 9-Chloroacridine-1,4-dione；9-chloroacridine-1,4-dione
• CAS: 1083096-00-7
• 化学式: C₁₃H₆ClNO₂
• 分子量: 243.649
• InChiKey: WWMKLWWDZFDXSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,4-dimethoxy-9-chloroacridine 在 ammonium cerium(IV) nitrate 作用下， 以 水 、 乙腈 为溶剂， 反应 0.33h， 以88%的产率得到9-chloro-1,4-acridinequinone
  参考文献：
  名称：

  Synthesis of Acridine–Quinone Systems—A Potential Electrochemical Fluorescent Switch

  摘要：

  The synthesis of various acridine-quinones is reported. The fluorescence-quenching quinone moiety has been incorporated into various acridine molecules, each having a different functionality at the ninth position of the acridine ring. It is envisaged that the quenching nature of the quinone will lead to the fluorescent properties of the acridine being controlled in a way similar to turning on a light switch.

  DOI：

  10.1080/00397910802154261

文献信息

• Synthesis of Acridine–Quinone Systems—A Potential Electrochemical Fluorescent Switch
  作者：Verity J. Litchfield、Robert B. Smith、Anthony M. Franklin、James Davis

  DOI：10.1080/00397910802154261

  日期：2008.9.29

  The synthesis of various acridine-quinones is reported. The fluorescence-quenching quinone moiety has been incorporated into various acridine molecules, each having a different functionality at the ninth position of the acridine ring. It is envisaged that the quenching nature of the quinone will lead to the fluorescent properties of the acridine being controlled in a way similar to turning on a light switch.