p-methoxyphenyl 3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1-3)-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1-6))-2,4-di-O-benzyl-β-D-mannopyranosyl-(1-4)-(2-deoxy-2-acetamido-β-D-glucopyranosyl-(1-6))-3-O-benzyl-2-deoxy-2-acetamido-β-D-glucopyranoside | 214608-45-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: p-methoxyphenyl 3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1-3)-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1-6))-2,4-di-O-benzyl-β-D-mannopyranosyl-(1-4)-(2-deoxy-2-acetamido-β-D-glucopyranosyl-(1-6))-3-O-benzyl-2-deoxy-2-acetamido-β-D-glucopyranoside
• CAS: 214608-45-4
• 化学式: C₁₀₄H₁₁₈N₂O₂₇
• 分子量: 1828.08
• InChiKey: NBFWDOBDBGTRKI-MROUKYBTSA-N

反应信息

• 作为反应物：
  描述：

  p-methoxyphenyl 3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1-3)-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1-6))-2,4-di-O-benzyl-β-D-mannopyranosyl-(1-4)-(2-deoxy-2-acetamido-β-D-glucopyranosyl-(1-6))-3-O-benzyl-2-deoxy-2-acetamido-β-D-glucopyranoside 在 乙二胺 作用下， 以 正丁醇 为溶剂， 反应 48.0h， 生成
  参考文献：
  名称：

  Synthetic study on a novel Asn-linked core structure: synthesis of a pentasaccharide α-d-Man-(1→3)-[α-d-Man-(1→6)]-β-d-Man-(1→4)-[β-d-GlcNAc-(1→6)]-β-d-GlcNAc→OMp11Mp=p-meth

  摘要：

  Synthesis of a pentasaccharide alpha-DMan-(1-->3)-[alpha-D-Man-(1-->6)]-beta-D-Man-(1-->4)-[beta-D-GlcNAc(1-->6)]-beta-D-GlcNAc-->OMp (2) is described. A comparison between the H-1 NMR data of 2 and those of a novel Asn-linked core structure 1 containing a new GlcNAc residue suggests an alpha-D-configuration for the new linkage. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0008-6215(98)00031-7
• 作为产物：
  描述：

  乙酸酐 、 以 甲醇 为溶剂， 生成 p-methoxyphenyl 3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1-3)-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1-6))-2,4-di-O-benzyl-β-D-mannopyranosyl-(1-4)-(2-deoxy-2-acetamido-β-D-glucopyranosyl-(1-6))-3-O-benzyl-2-deoxy-2-acetamido-β-D-glucopyranoside
  参考文献：
  名称：

  Synthetic study on a novel Asn-linked core structure: synthesis of a pentasaccharide α-d-Man-(1→3)-[α-d-Man-(1→6)]-β-d-Man-(1→4)-[β-d-GlcNAc-(1→6)]-β-d-GlcNAc→OMp11Mp=p-meth

  摘要：

  Synthesis of a pentasaccharide alpha-DMan-(1-->3)-[alpha-D-Man-(1-->6)]-beta-D-Man-(1-->4)-[beta-D-GlcNAc(1-->6)]-beta-D-GlcNAc-->OMp (2) is described. A comparison between the H-1 NMR data of 2 and those of a novel Asn-linked core structure 1 containing a new GlcNAc residue suggests an alpha-D-configuration for the new linkage. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0008-6215(98)00031-7