| 847375-07-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 847375-07-9
• 化学式: C₁₃H₂₇AlO
• 分子量: 226.338
• InChiKey: IAIUSFCQUGMFID-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  10-十一烯-1-醇 、 三甲基铝 以 癸烷 为溶剂， 生成
  参考文献：
  名称：

  Investigation of insertion reaction of 10-undecen-1-ol protected with alkylaluminum in En(Ind)2ZrCl2/MAO catalyst system

  摘要：

  In this study, insertion reaction of 10-undecen-1-ol (Un-OH) into the metallocene active center was investigated in the absence of olefin monomers. 10-Undecen-1-ol protected with trialkylaluminum (Un-O-AlR2,; R=Me, Et, n-Bu, i-Bu) was treated with an En(Ind)(2)ZrCl2/MAO catalyst system. The reactant, after quenched with HCl, was analyzed to identify the resulting alcohol compounds by gas chromatography with the comparison of authentic samples and NMR methods. As a result, undecanol (saturated Un-OH) and other alcohol compounds, in which alkyl groups derived from trialkylaluminum were incorporated into Un-OH, were found mainly in the resulting compounds, supporting that Un-O-AlR2, was inserted into the metallocene active center in the absence of olefin monomers. The mechanism of the insertion reaction of Un-O-AlR2 was also discussed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.07.010