cis-[(η¹-CH₂(C₄H₂O)CO₂CH₃)PtCl(triphenylphosphine)₂] | 1392235-39-0

• 英文名称: cis-[(η¹-CH₂(C₄H₂O)CO₂CH₃)PtCl(triphenylphosphine)₂]
• 英文别名: cis-[(η¹-CH₂(C₄H₂O)CO₂CH₃)PtCl(PPh₃)₂]
• CAS: 1392235-39-0
• 化学式: C₄₃H₃₇ClO₃P₂Pt
• 分子量: 894.245
• InChiKey: BUEYADSQPBZNMR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 cis-[(η¹-CH₂(C₄H₂O)CO₂CH₃)PtCl(triphenylphosphine)₂] 、 silver tetrafluoroborate 以 甲苯 为溶剂， 反应 8.0h， 以280 mg的产率得到[(η³-CH₂(C₄H₂O)CO₂CH₃)Pt(PPh₃)₂](tetrafluoroborate)*dichloromethane
  参考文献：
  名称：

  η³-Furfuryl and η³-Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans

  摘要：

  A number of cationic and neutral eta(3)-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous eta(3)-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.

  DOI：

  10.1021/om300568z
• 作为产物：
  描述：

  5-(氯甲基)-2-糠酸甲酯 、 乙烯双(三苯基磷)铂 以 甲苯 为溶剂， 反应 1.0h， 生成 cis-[(η¹-CH₂(C₄H₂O)CO₂CH₃)PtCl(triphenylphosphine)₂]
  参考文献：
  名称：

  η³-Furfuryl and η³-Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans

  摘要：

  A number of cationic and neutral eta(3)-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous eta(3)-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.

  DOI：

  10.1021/om300568z