1,10-phenanthroline-bis-(4,6-dimethylpyrimidine-2-thiolato)manganese(II) | 169967-74-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 1,10-phenanthroline-bis-(4,6-dimethylpyrimidine-2-thiolato)manganese(II)
• CAS: 169967-74-2
• 化学式: C₂₄H₂₂MnN₆S₂
• 分子量: 513.549
• InChiKey: IQSMKUALPAWFLM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,6-二甲基-2-巯基嘧啶 、 锰 、 1,10-菲罗啉 以 乙腈 为溶剂， 生成 1,10-phenanthroline-bis-(4,6-dimethylpyrimidine-2-thiolato)manganese(II)
  参考文献：
  名称：

  Electrochemical synthesis of manganese(II) complexes of pyrimidine-2-thiones: The crystal structures of bis-4,6-dimethylpyrimidyl-2,2′-disulphide and 1,10-phenanthroline-bis (4,6-dimethylpyrimidine-2-thiolato)manganese(II)

  摘要：

  The electrochemical oxidation of anodic manganese in an acetonitrile solution of pyrimidine-2-thione (pymtH) or 4,6-dimethylpyrimidine-2-thione (4,6-Me(2)pymtH) and nitrogen donor bidentate ligands such as 1,10-phenanthroline (phen) or 2,2'-bipyridine (bipy), yielded mixed complexes [Mn(pymt)(2)phen], [Mn(4,6-Me(2)pymt)(2)phen] and [Mn(4,6Me(2)pymt)(2)bipy]. The crystal structures of bis-4,6-dimethylpyrimidyl-2-2'disulphide and 1,10-phenanthroline-bis-(4,6-dimethylpyrimidine-2-thiolato)managanese(II) have been determined by X-ray diffraction. In the manganese complex the metal has a distorted octahedral trans-MnS2N4 geometry with one nitrogen atom of each pyrimidine ligand uncoordinated.

  DOI：

  10.1016/0277-5387(95)00218-h