undecafluorocyclohexanol | 146467-39-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: undecafluorocyclohexanol
• 英文别名: 1,2,2,3,3,4,4,5,5,6,6-Undecafluorocyclohexanol；1,2,2,3,3,4,4,5,5,6,6-undecafluorocyclohexan-1-ol
• CAS: 146467-39-2
• 化学式: C₆HF₁₁O
• 分子量: 298.056
• InChiKey: FXEMDAWPSGKRNC-UHFFFAOYSA-N

物化性质

• 沸点：
  106.1±40.0 °C(Predicted)
• 密度：
  1.78±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  癸氟环己酮 在 氢氟酸 作用下， 生成 undecafluorocyclohexanol
  参考文献：
  名称：

  全氟醇c -C 6 F 11 OH，c -C 6 F 10 -1,1-（OH）2和c -C 6 F 10 -1-（CF 3）OH †

  摘要：

  通过将氟化氢添加到相应的酮中来制备热不稳定的α-氟醇十一氟环己醇（c -C 6 F 11 OH）。通过其醇盐[NMe 4 ] + [C 7 F 13 O] -的质子化反应获得c -C 6 F 10（CF 3）OH 。通过酸处理相应的醇盐[NMe 4 ] + [C 6 F ] ，制备十氟环己烷-1,1-二醇（c -C 6 F 10（OH）2）用硫酸得到11 O] -，得到（ c -C 6 F 10（OH） 2）和氟磺酸。的结构Ç -C 6 ˚F 10（CF 3）OH·2H 2 O和的（ C ^ -C 6 ˚F 10（OH） 2）通过单晶X-射线和气相电子衍射研究，阐明。

  DOI：

  10.1039/c8cc05148h

文献信息

• Method involving thermally sensitive alpha-amidoacetyl or beta-amidopropionyl linkages
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0433034A2

  公开（公告）日：1991-06-19

  Compounds containing alpha-amidoacetyl linkages are described that are thermally labile and yield nucleophilic and azlactone products. Nucleophiles are useful as curing agents for epoxy resin sealants and adhesives and azlactones are useful in crosslinking systems for polymers.

  介绍了含有α-氨基乙酰基连接的化合物，这些化合物具有热亲和性，可产生亲核产物和氮内酯产物。亲核物可用作环氧树脂密封剂和粘合剂的固化剂，氮内酯可用于聚合物的交联系统。
• Superomniphobic coatings and methods of preparation
  申请人：UT-Battelle, LLC

  公开号：US11311907B2

  公开（公告）日：2022-04-26

  A composition useful for producing a superomniphobic coating on a substrate, the composition comprising a colloidal suspension of a fluorinated siloxane in a non-silicon-containing fluorinated solvent. In some embodiments, the composition further comprises particles of a hydrophobized metal oxide, e.g., silicon oxide, wherein the hydrophobized metal oxide may be fluorinated. In some embodiments, the composition further comprises a non-silicon-containing fluorinated polymer. The invention is also directed to methods for making the above composition. The invention is also directed to methods for using the above-described composition for rendering a substrate superomniphobic. The aforesaid method comprises depositing a liquid coating solution onto a substrate to form a coated substrate, followed by subjecting the coated substrate to a drying step to remove a liquid phase of the liquid coating solution, wherein the liquid coating solution comprises a colloidal suspension of a fluorinated siloxane in a non-silicon-containing fluorinated solvent.

  一种用于在基材上制作超疏磷涂层的组合物，该组合物包括氟化硅氧烷在非含硅氟化溶剂中的胶体悬浮液。在某些实施方案中，组合物进一步包含疏水性金属氧化物（如氧化硅）颗粒，其中疏水性金属氧化物可以是氟化的。在某些实施方案中，组合物进一步包含非含硅氟聚合物。本发明还涉及制造上述组合物的方法。本发明还涉及使用上述组合物使基底具有超疏水性的方法。上述方法包括将液体涂层溶液沉积到基底上以形成涂层基底，然后将涂层基底置于干燥步骤中以除去液体涂层溶液的液相，其中液体涂层溶液包括氟化硅氧烷在非含硅含氟溶剂中的胶体悬浮液。
• Process for alkali saponification of polymer film
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20030194668A1

  公开（公告）日：2003-10-16

  A process for alkali saponification of polymer film is disclosed. The process comprises the steps of applying solution of an alkali onto a polymer film having a temperature of not lower than room temperature, and washing away the alkaline solution from the film.

  本发明公开了一种聚合物薄膜碱皂化工艺。该工艺包括以下步骤：在温度不低于室温的聚合物薄膜上涂抹碱溶液，并从薄膜上洗去碱溶液。
• Method of alkali saponifying polymer film, surface-saponified cellulose ester film and optical film
  申请人：Mutou Kunio

  公开号：US20060269768A1

  公开（公告）日：2006-11-30

  A for alkali saponifying a polymer film is provided and includes the steps of: coating a polymer film at room temperature or higher with an alkali solution having specific ratios among an alkali, a high-boiling solvent, water and water; and the step of washing away the alkali solution from the polymer film.
• SUPEROMNIPHOBIC COATINGS AND METHODS OF PREPARATION
  申请人：UT-Battelle, LLC

  公开号：US20190193115A1

  公开（公告）日：2019-06-27

  A composition useful for producing a superomniphobic coating on a substrate, the composition comprising a colloidal suspension of a fluorinated siloxane in a non-silicon-containing fluorinated solvent. In some embodiments, the composition further comprises particles of a hydrophobized metal oxide, e.g., silicon oxide, wherein the hydrophobized metal oxide may be fluorinated. In some embodiments, the composition further comprises a non-silicon-containing fluorinated polymer. The invention is also directed to methods for making the above composition. The invention is also directed to methods for using the above-described composition for rendering a substrate superomniphobic. The aforesaid method comprises depositing a liquid coating solution onto a substrate to form a coated substrate, followed by subjecting the coated substrate to a drying step to remove a liquid phase of the liquid coating solution, wherein the liquid coating solution comprises a colloidal suspension of a fluorinated siloxane in a non-silicon-containing fluorinated solvent.