Tetradecanoic acid (2R,3S,4R,5R)-6-hydroxy-2-((2R,3R,4R,5S,6R)-4-hydroxy-5-phosphonooxy-3-tetradecanoylamino-6-tetradecanoyloxymethyl-tetrahydro-pyran-2-yloxymethyl)-5-tetradecanoylamino-4-tetradecanoyloxy-tetrahydro-pyran-3-yl ester; compound with triethyl-amine | 88862-39-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Tetradecanoic acid (2R,3S,4R,5R)-6-hydroxy-2-((2R,3R,4R,5S,6R)-4-hydroxy-5-phosphonooxy-3-tetradecanoylamino-6-tetradecanoyloxymethyl-tetrahydro-pyran-2-yloxymethyl)-5-tetradecanoylamino-4-tetradecanoyloxy-tetrahydro-pyran-3-yl ester; compound with triethyl-amine
• CAS: 88862-39-9
• 化学式: C₆H₁₅N*C₈₂H₁₅₅N₂O₁₇P
• 分子量: 1573.3
• InChiKey: OLJCCVDWSMMIMD-FFAPBJRDSA-N

反应信息

• 作为产物：
  描述：

  Tetradecanoic acid (2R,3S,4R,5R,6R)-4-benzyloxy-3-(benzyloxy-phenoxy-phosphoryloxy)-6-((2R,3S,4R,5R)-6-hydroxy-5-tetradecanoylamino-3,4-bis-tetradecanoyloxy-tetrahydro-pyran-2-ylmethoxy)-5-tetradecanoylamino-tetrahydro-pyran-2-ylmethyl ester 在 platinum(IV) oxide 氢气 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 以92%的产率得到Tetradecanoic acid (2R,3S,4R,5R)-6-hydroxy-2-((2R,3R,4R,5S,6R)-4-hydroxy-5-phosphonooxy-3-tetradecanoylamino-6-tetradecanoyloxymethyl-tetrahydro-pyran-2-yloxymethyl)-5-tetradecanoylamino-4-tetradecanoyloxy-tetrahydro-pyran-3-yl ester; compound with triethyl-amine
  参考文献：
  名称：

  脂质a磷酸化基本结构的化学合成

  摘要：

  1-α单磷酸（），4'-磷酸（），和1-α，4'-二磷酸（的）6-O-（2-脱氧-2-十四酰氨-6-O-十四烷酰基- β-D-制备吡喃葡萄糖基）-2-脱氧-2-十四烷酰氨基-3，4-二-0-十四烷酰-D-吡喃葡萄糖，以阐明磷酸部分在脂质A内毒素活性中的作用。

  DOI：

  10.1016/s0040-4039(01)92910-7