1,1-bis-hydroxymethyl-2-methyl-cyclohexane | 66810-07-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1-bis-hydroxymethyl-2-methyl-cyclohexane
• 英文别名: 1,1-Bis-hydroxymethyl-2-methyl-cyclohexan；2-methyl-1,1-cyclohexanedimethanol；1,1-Cyclohexanedimethanol, 2-methyl-；[1-(hydroxymethyl)-2-methylcyclohexyl]methanol
• CAS: 66810-07-9
• 化学式: C₉H₁₈O₂
• 分子量: 158.241
• InChiKey: YUNWVKPGEQYTIF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1-bis-hydroxymethyl-2-methyl-cyclohexane 在 三溴化磷 作用下， 生成 1,1-bis-bromomethyl-2-methyl-cyclohexane
  参考文献：
  名称：

  Shortridge et al., Journal of the American Chemical Society, 1948, vol. 70, p. 948

  摘要：

  DOI：
• 作为产物：
  描述：

  5r-Methyl-Δ¹-cyclohexen-4t-carbaldehyd 在 甲醇 、 氢氧化钾 、 乙醇 、 镍 作用下， 生成 1,1-bis-hydroxymethyl-2-methyl-cyclohexane
  参考文献：
  名称：

  Shortridge et al., Journal of the American Chemical Society, 1948, vol. 70, p. 948

  摘要：

  DOI：

文献信息

• Materials leading to improved dental composites and dental composites made therefrom
  申请人：Anton Robert Douglas

  公开号：US20060258770A1

  公开（公告）日：2006-11-16

  This invention relates to composite materials for restorative dentistry. More particularly, it relates to new components for dental composites, which impart an attractive combination of good mechanical properties and low shrinkage.

  本发明涉及修复牙科的复合材料。更具体地说，它涉及用于牙科复合材料的新组分，这些组分赋予了良好的机械性能和低收缩率的有吸引力的组合。
• Resist ink composition
  申请人：——

  公开号：US20030022958A1

  公开（公告）日：2003-01-30

  The present invention provides a resist ink composition comprising a compound (a) having at least one oxetanyl group and at least one epoxy group within the same molecule and a compound (b) capable of initiating cationic polymerization under irradiation by an active energy ray and/or under heat. This resist ink composition has high photosensitivity and enables the final curing by a brief heating and the cured film exhibits good physical properties.

  本发明提供了一种抗蚀墨水组合物，包括一个化合物（a），其分子内至少具有一个环氧乙烷基团和至少一个环氧基团，以及一种化合物（b），能够在活性能量射线辐射和/或热下启动阳离子聚合。该抗蚀墨水组合物具有高感光性，可以通过短暂加热最终固化，固化薄膜具有良好的物理性能。
• Polymerizable composition, cured material thereof and method for manufacturing the same
  申请人：——

  公开号：US20020161068A1

  公开（公告）日：2002-10-31

  The present invention provides a polymerizable composition comprising (a) an alicyclic alkane having at least one oxetanyl group and at least one epoxy group within the same molecule and (b) a compound capable of initiating cationic polymerization under irradiation of an active energy ray and/or under heat exhibits high activity in the photo- or heat-cationic ring-opening polymerization exhibiting high activity, e.g., rapid polymerizability, rapid curability, under irradiation of an active energy ray and/or under heat. The present invention also provides a polymerization product thereof.

  本发明提供了一种可聚合的组合物，包括（a）至少具有一个环氧基团和至少一个氧杂环基团的脂环烷，并且这两种基团在同一分子中，以及（b）在活性能量射线的照射和/或热下能够启动阳离子聚合的化合物，表现出高活性的光或热阳离子开环聚合，例如，在活性能量射线的照射和/或热下具有快速聚合性和快速固化性。本发明还提供了其聚合产物。
• POLYMERIZABLE COMPOUND AND CURABLE COMPOSITION COMPRISING SAME
  申请人：Ooga Kazuhiko

  公开号：US20120232183A1

  公开（公告）日：2012-09-13

  Provided are a polymerizable compound, a photocurable composition, and a photocurable moisture-proof insulating coating material for mounting circuit boards, which reduce environmental impact, excel in surface curability at low irradiation dose, and have high adhesion to substrate materials. The compound according to the present invention has a structural unit derived from a dimerdiol and has, as an end group, a group represented by formula (1): wherein R 1 represents H or CH 3 and R 2 represents a hydrocarbon group having 2 to 12 carbon atoms, at an end thereof. Preferably, the compound has, as end groups, the group represented by formula (1) and a group represented by formula (2): wherein R 3 s each independently represent CH 3 or CH 2 CH 3 , and R 4 represents a hydrocarbon group having 3 to 9 carbon atoms, at the end thereof. The structure having the structural unit derived from a dimerdiol is preferably represented by formula (3):

  本发明提供了一种可聚合化合物、一种光固化组合物和一种用于安装电路板的光固化防潮绝缘涂料材料，其减少环境影响，在低辐射剂量下具有优异的表面固化性能，并且对基材具有高粘附性。本发明的化合物具有从二聚醇衍生的结构单元，并具有式（1）所表示的基团作为末端基团，其中R1代表H或CH3，R2代表具有2到12个碳原子的烃基，在其末端。最好的情况是，该化合物具有由式（1）和式（2）所表示的基团作为末端基团：其中R3各自独立地表示CH3或CH2CH3，R4表示具有3到9个碳原子的烃基，在其末端。具有从二聚醇衍生的结构单元的结构最好是由式（3）所表示的。
• CURABLE COMPOSITION
  申请人：SHOWA DENKO K.K.

  公开号：US20140309326A1

  公开（公告）日：2014-10-16

  Provided are a polymerizable compound, a photocurable composition, and a photocurable moisture-proof insulating coating material for mounting circuit boards, which reduce environmental impact, excel in surface curability at low irradiation dose, and have high adhesion to substrate materials. The compound according to the present invention has a structural unit derived from a dimerdiol and has, as an end group, a group represented by formula (1): wherein R 1 represents H or CH 3 and R 2 represents a hydrocarbon group having 2 to 12 carbon atoms, at an end thereof. Preferably, the compound has, as end groups, the group represented by formula (1) and a group represented by formula (2): wherein R 3 s each independently represent CH 3 or CH 2 CH 3 , and R 4 represents a hydrocarbon group having 3 to 9 carbon atoms, at the end thereof. The structure having the structural unit derived from a dimerdiol is preferably represented by formula (3):

  本发明提供了一种可聚合化合物、一种光固化组合物和一种用于安装电路板的光固化防潮绝缘涂料材料，其可降低环境影响，在低辐照剂量下具有优异的表面固化性能，并且对基底材料具有高粘附性。根据本发明，该化合物具有源自二元醇二聚体的结构单元，并且具有式（1）所表示的基团作为末端基团。其中，R1表示H或CH3，R2表示具有2到12个碳原子的烃基，在其末端。最好的情况是，该化合物具有式（1）所表示的基团和式（2）所表示的基团作为末端基团。其中，R3分别独立表示CH3或CH2CH3，R4表示具有3到9个碳原子的烃基，在其末端。具有源自二元醇二聚体的结构单元的结构最好用式（3）表示：