[Fe(4,4'-bis-1,2,4-triazole)2(isothiocyanate)2]*H2O | 109528-75-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Fe(4,4'-bis-1,2,4-triazole)2(isothiocyanate)2]*H2O
• CAS: 109528-75-8
• 化学式: C₁₀H₈FeN₁₄S₂*H₂O
• 分子量: 462.262
• InChiKey: CXBKOVMGFKDOIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 ferrous(II) sulfate heptahydrate 、 4-(1,2,4-三唑-4-基)-1,2,4-三唑 在 ascorbic acid 作用下， 以 水 为溶剂， 生成 [Fe(4,4'-bis-1,2,4-triazole)2(isothiocyanate)2]*H2O
  参考文献：
  名称：

  Observation of the spin-crossover in [Fe(btr)2(NCS)2]·H2O (btr=4,4′-bis-1,2,4-triazole) with μSR

  摘要：

  The electronic spin transition in [Fe(btr)(2)(NCS)(2)] . H2O (btr = 4,4'-bis-1,2,4-triazole) is probed by longitudinal field muon spin relaxation measurements. The muSR spectra could be analyzed with two different components, corresponding to two muon sites. For both components, an increase in magnetic fluctuations is observed at the LS --> HS transition, i.e. crossing the spin transition temperature coming from low temperature, if a sufficiently high field is applied. Even below the transition temperature, magnetic fluctuations are still found. For one of the two union sites, muonium formation is clearly found below the spin-crossover temperature. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2004.07.016