dimethylbromogermane | 53445-65-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: dimethylbromogermane
• 英文别名: Bromo(dimethyl)germane；bromo(dimethyl)germane
• CAS: 53445-65-1
• 化学式: C₂H₇BrGe
• 分子量: 183.572
• InChiKey: GJFYIHOTIUAEIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.36
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  溴苯 、 dimethylbromogermane 在 Mg 作用下， 以 not given 为溶剂， 生成 bromodimethylphenylgermane
  参考文献：
  名称：

  Gas phase reaction of nucleogenic dimethylgermylium cations with benzene

  摘要：

  Reaction of nucleogenic dimethylgermylium cations with benzene in the gas phase was studied by the radiochemical method. The formation of the products of germylation of benzene, dimethylphenylgermane, and phenylgermane is indicative of the formation of dimethylgermylium cations by the beta-decay of tritium in the molecule of dimethylditritium germane. Dimethylgermylium cations are shown to undergo a rearrangement in the course of the reaction with benzene, which is consistent with the earlier results of quantum-chemical calculations.

  DOI：

  10.1134/s1070363210090070

文献信息

• Transition-metal carbonyl derivatives of the germanes. Part 7. Properties of complexes containing dimethylgermyliron carbonyl groups and their interconversion
  作者：Alan Bonny、Kenneth M. Mackay

  DOI：10.1039/dt9780000722

  日期：——

  The complex [Fe(CO)4(GeMe2H)2](1) is unstable with respect to condensation to [Fe(CO)4(GeMe2)}2](2) eliminating GeMe2H2. In the light, or very slowly in the dark, (2) loses CO and is probably converted to [Fe2(CO)7-(GeMe2)2](3). The i.r., 1H n.m.r., and mass spectra of these complexes are reported.

  配合物[Fe（CO）4（GeMe 2 H）2 ]（1）对于与消除GeMe 2 H 2的[Fe（CO）4（GeMe 2）} 2 ]（2）缩合而言是不稳定的。在光下，或在黑暗中非常缓慢，（2）会损失一氧化碳，并可能转化为[Fe 2（CO）7-（GeMe 2）2 ]（3）。报告了这些配合物的ir，1 H nmr和质谱。
• Audett, Judy A. nee Christie; Mackay, Kenneth M., Journal of the Chemical Society, Dalton Transactions
  作者：Audett, Judy A. nee Christie、Mackay, Kenneth M.

  DOI：——

  日期：——
• Gas phase reaction of nucleogenic dimethylgermylium cations with benzene
  作者：D. L. Myalochkin、T. A. Kochina、V. V. Avrorin、D. V. Vrazhnov、E. N. Sinotova

  DOI：10.1134/s1070363210090070

  日期：2010.9

  Reaction of nucleogenic dimethylgermylium cations with benzene in the gas phase was studied by the radiochemical method. The formation of the products of germylation of benzene, dimethylphenylgermane, and phenylgermane is indicative of the formation of dimethylgermylium cations by the beta-decay of tritium in the molecule of dimethylditritium germane. Dimethylgermylium cations are shown to undergo a rearrangement in the course of the reaction with benzene, which is consistent with the earlier results of quantum-chemical calculations.