[Zn(II)(N,N'-ethylene-bis(acetylacetoniminate)] | 96114-86-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: [Zn(II)(N,N'-ethylene-bis(acetylacetoniminate)]
• 英文别名: [Zn(N,N'-ethylenebis(acetylacetoniminato))]；[Zn(acacen)]
• CAS: 96114-86-2
• 化学式: C₁₂H₁₈N₂O₂Zn
• 分子量: 287.677
• InChiKey: WYATZUHSHYKUOH-ALGRVRKVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N'-乙烯二(4-氧代-2-戊烷亚胺) 、 diethylzinc 以 benzene 为溶剂， 生成 [Zn(II)(N,N'-ethylene-bis(acetylacetoniminate)]
  参考文献：
  名称：

  Mass spectrometric study of the overheated vapor over Ni(II), Cu(II), and Zn(II) N,N′-ethylenebis(acetylacetoniminato) complexes

  摘要：

  A mass spectrometric study of the overheated vapor over the complexes Ni(acacen), Cu(acacen), and Zn(acacen) (H(2)acacen = N,N'-ethylenebis(acetylacetonimine)) has been carried out in the temperature range of 180-760A degrees C. Irrespective of the degree of overheating, the vapor phases over all of these compounds contain no ions heavier than the molecular ion [MO(2)N(2)C(12)H(18)](+). The existence of molecular ions in the overheated vapor in the double-chamber two-temperature effusion cell is evidence of the high thermal stability of the complexes. The onset temperature of the thermal decomposition of Ni(acacen), Cu(acacen), and Zn(acacen) is 690, 610, and 560A degrees C, respectively. The way of fragmentation of the chelates under electron impact ionization depends on the nature of the metal.

  DOI：

  10.1134/s0036023609120225