phenyl 6-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-galactopyranoside | 945634-61-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: phenyl 6-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-galactopyranoside
• CAS: 945634-61-7
• 化学式: C₆₇H₆₈O₁₀S
• 分子量: 1065.34
• InChiKey: PUPNIMNBPBWWNE-OIRISZAWSA-N

反应信息

• 作为反应物：
  描述：

  phenyl 6-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-galactopyranoside 在 N-溴代丁二酰亚胺(NBS) 、 水 作用下， 以 丙酮 为溶剂， 反应 0.5h， 生成 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1→6)-2,3,4-tri-O-benzyl-β-D-galactopyranose 、 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl-(1→6)-2,3,4-tri-O-benzyl-α-D-galactopyranose
  参考文献：
  名称：

  Synthesis of a Tetrasaccharide Glycosyl Glycerol. Precursor to Glycolipids of Meiothermus taiwanensis ATCC BAA-400

  摘要：

  Synthesis of a tetrasaccharide glycosyl glycerol, the core structure of glycoglycerolipid from Meiothermus taiwanensis ATCC BAA-400, was described. A one-pot glycosylation with three components was employed as a key step.

  DOI：

  10.1021/jo070629l
• 作为产物：
  描述：

  2,3,4,6-tetra-O-benzyl-D-galactopyranosyl acetate 在 碘代三甲硅烷 、 四丁基碘化铵 、 N,N-二异丙基乙胺 作用下， 以 二氯甲烷 、 苯 为溶剂， 反应 6.0h， 生成 phenyl 6-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-galactopyranoside
  参考文献：
  名称：

  Synthesis of a Tetrasaccharide Glycosyl Glycerol. Precursor to Glycolipids of Meiothermus taiwanensis ATCC BAA-400

  摘要：

  Synthesis of a tetrasaccharide glycosyl glycerol, the core structure of glycoglycerolipid from Meiothermus taiwanensis ATCC BAA-400, was described. A one-pot glycosylation with three components was employed as a key step.

  DOI：

  10.1021/jo070629l