7-(2,4-Me2)C9H4NNCHC6H3-5-Br-2-OH | 959867-29-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7-(2,4-Me2)C9H4NNCHC6H3-5-Br-2-OH
• 英文别名: 2,4-Dibromo-6-[(2,4-dimethylquinolin-7-yl)iminomethyl]phenol
• CAS: 959867-29-9
• 化学式: C₁₈H₁₄Br₂N₂O
• 分子量: 434.13
• InChiKey: AZSWWKRQYBGQNG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  45.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  7-(2,4-Me2)C9H4NNCHC6H3-5-Br-2-OH 、 diethylzinc 以 甲苯 为溶剂， 以88%的产率得到(7-(2,4-Me2)C9H4NNCH(O)C6H2Br2-3,5)2Zn
  参考文献：
  名称：

  Bis-salicylaldiminato zinc complexes: Syntheses, characterization and luminescent properties

  摘要：

  The syntheses of four four-coordinate zinc(II) complexes,[GRAPHICS]((ArN)-N-1=(HCArO)-O-2)(2)Zn (Ar-1 = 7-(2,4-Me-2)C9H4N, Ar-2 = C6H4 (2a); Ar-1 = 7-(2,4-Me-2)C9H4N, Ar-2 = 3,5-(Bu2C6H2)-Bu-t (2b); Ar-1 = 7-(2,4-Me-2)C9H4N, Ar-2 = 5-BrC6H3 (2c); Ar-1 = 7-(2,4-Me-2)C9H4N, Ar-2 = 3,5-Br2C6H2 (2d)) are described. Complexes 2a-2d were synthesized by the reaction of ZnEt2 with 2 equiv. of the corresponding ligand. Ligands 1a-1d and the corresponding zinc(II) complexes 2a-2d were characterized by elemental analysis, IR, H-1 and C-13 NMR spectroscopy. The molecular structure of complex 2b was determined by single crystal X-ray crystallography. Luminescent properties of the ligands 1a-1d and complexes 2a-2d in both solution and the solid state were studied. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.07.006