2-(2'-quinolinyl)phenyltellurium(IV) tribromide | 119408-45-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2-(2'-quinolinyl)phenyltellurium(IV) tribromide
• 英文别名: 2-(quinolin-2-yl)phenyltellurium(IV) tribromide
• CAS: 119408-45-6
• 化学式: C₁₅H₁₀Br₃NTe
• 分子量: 571.563
• InChiKey: DQUOPTUWRJGWAF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.23
• 重原子数：
  20.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.89
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  2-(2'-quinolinyl)phenyltellurium(IV) tribromide 在 一水合肼 作用下， 以 乙醇 为溶剂， 反应 0.25h， 生成 2-(quinolin-2-yl)phenyltellurium(II) bromide
  参考文献：
  名称：

  Al-Salim, Najih; West, Antony A.; McWhinnie, William R., Journal of the Chemical Society, Dalton Transactions, 1988, p. 2363 - 2372

  摘要：

  DOI：
• 作为产物：
  描述：

  2-苯基喹啉 在 mercury(II) diacetate 、 溴化碲 、 lithium chloride 作用下， 生成 2-(2'-quinolinyl)phenyltellurium(IV) tribromide
  参考文献：
  名称：

  Al-Salim, Najih; West, Antony A.; McWhinnie, William R., Journal of the Chemical Society, Dalton Transactions, 1988, p. 2363 - 2372

  摘要：

  DOI：

文献信息

• Aspects of the chemistry of diorgano tritellurides
  作者：Anatoly G. Maslakov、Martin R. Greaves、William R. McWhinnie、Sean L.W. McWhinnie

  DOI：10.1016/0022-328x(94)80040-5

  日期：1994.4

  The synthetic methods available for diorgano tritellurides, which normally give only poor to moderate yields of product, are evaluated. Most reliable when organic groups such as 2-(2'-pyridyl)phenyl- are involved is the reaction of Te2- with the organotellurenyl halide in DMF. Other methods require a final oxidative step. Reactions of Te-2(2-) with organotellurenyl halides in DMF give deep red solutions which quantitatively deposit tellurium on exposure to air; successful syntheses of (RTe)2Se2 (R = 2-(2'-pyridyl or 2'-quinolinyl)phenyl-) were carried out by use of Se-2(2-) in DMF solution. The air stable bis-[2-(p-tolyliminomethyl)phenyl] tritelluride is reported, and its Te-125 and Raman spectral data presented. The role of intra-molecular coordination in stabilising these molecules may be a secondary one; the steric effect of a bulky 2-substituent on the tellurated phenyl-ring may be more significant.