[(2R,3R,4S,5R,6R)-3,5-diacetyloxy-4-[(2S,3R,4S,5R,6R)-3,5-diacetyloxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,5-diacetyloxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxan-2-yl]oxyoxan-2-yl]oxy-6-pent-4-enoxyoxan-2-yl]methyl acetate | 801220-69-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(2R,3R,4S,5R,6R)-3,5-diacetyloxy-4-[(2S,3R,4S,5R,6R)-3,5-diacetyloxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,5-diacetyloxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxan-2-yl]oxyoxan-2-yl]oxy-6-pent-4-enoxyoxan-2-yl]methyl acetate
• CAS: 801220-69-9
• 化学式: C₅₅H₇₆O₃₄
• 分子量: 1281.19
• InChiKey: LNMIXNXYUWTYSE-CMOPJJJWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  89
• 可旋转键数：
  41
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  416
• 氢给体数：
  0
• 氢受体数：
  34

反应信息

• 作为反应物：
  描述：

  [(2R,3R,4S,5R,6R)-3,5-diacetyloxy-4-[(2S,3R,4S,5R,6R)-3,5-diacetyloxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,5-diacetyloxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxan-2-yl]oxyoxan-2-yl]oxy-6-pent-4-enoxyoxan-2-yl]methyl acetate 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of Epoxyalkyl (1→3)‐β‐D‐Oligoglucosides

  摘要：

  We describe an approach for the synthesis of (1 --> 3)-beta-D-oligosaccharide derivatives 10-18. 1-9 were synthesized by treating peracetylated (1 --> 3)-beta-D-oligosaccharides with the corresponding alkenyl alcohols and Lewis acid (SnCl4) catalyst. Epoxidation of the corresponding alkenyl oligoglucosides took place by m-CPBA. NaOMe in dry methanol was used for the deacetylation of the blocked derivatives, to give 10-18 in overall yields of 25-32%.

  DOI：

  10.1081/scc-200032424
• 作为产物：
  描述：

  4-戊烯-1-醇 、 在 四氯化锡 作用下， 以 1,2-二氯乙烷 为溶剂， 生成 [(2R,3R,4S,5R,6R)-3,5-diacetyloxy-4-[(2S,3R,4S,5R,6R)-3,5-diacetyloxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,5-diacetyloxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxan-2-yl]oxyoxan-2-yl]oxy-6-pent-4-enoxyoxan-2-yl]methyl acetate
  参考文献：
  名称：

  Synthesis of Epoxyalkyl (1→3)‐β‐D‐Oligoglucosides

  摘要：

  We describe an approach for the synthesis of (1 --> 3)-beta-D-oligosaccharide derivatives 10-18. 1-9 were synthesized by treating peracetylated (1 --> 3)-beta-D-oligosaccharides with the corresponding alkenyl alcohols and Lewis acid (SnCl4) catalyst. Epoxidation of the corresponding alkenyl oligoglucosides took place by m-CPBA. NaOMe in dry methanol was used for the deacetylation of the blocked derivatives, to give 10-18 in overall yields of 25-32%.

  DOI：

  10.1081/scc-200032424