bis[N-(2-iodo)-naphthaldiminato]copper(II) | 488090-69-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: bis[N-(2-iodo)-naphthaldiminato]copper(II)
• CAS: 488090-69-3
• 化学式: C₃₄H₂₂CuI₂N₂O₂
• 分子量: 807.916
• InChiKey: NUVDMWBGFYNGGJ-BPLVGVCGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) acetate monohydrate 、 N-(2-iodo)-naphthaldimine 以 甲醇 、 乙腈 为溶剂， 以65%的产率得到bis[N-(2-iodo)-naphthaldiminato]copper(II)
  参考文献：
  名称：

  Crystal structure and spectroscopic studies of bis[N-(2-iodo)-naphthaldiminato]copper(II)

  摘要：

  The Schiff base complex bis[N-(2-iodo)-naphthaldiminato]copper(II) [Cu(C17H11NOI)(2)] (1) has been studied by elemental analysis, IR techniques and the structure of the compound has been examined crystallography. The compound 1 crystallizes in the monoclinic space group P2(1)/c with a = 8.229(2) Angstrom, b = 15.840(4) Angstrom, c = 11.389(3) Angstrom, beta = 104.49(2)degrees (R = 0.053 for 2507 reflections [I > 2sigma(I)]). It has crystallographic inversion symmetry. Two bidentate Schiff base ligand 1 coordinate to the Cu atom in a square-planar arrangement. The Cu-N and Cu-O distances are 1.990(2) and 1.896(2) Angstrom, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(02)00188-6