4,4-bis(ethoxymethyl)-1,6-heptadiyne | 957198-81-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,4-bis(ethoxymethyl)-1,6-heptadiyne
• CAS: 957198-81-1
• 化学式: C₁₃H₂₀O₂
• 分子量: 208.301
• InChiKey: JJJXHYYRGQYIQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.09
• 重原子数：
  15.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  4,4-bis(ethoxymethyl)-1,6-heptadiyne 、 碘苯 在 bis-triphenylphosphine-palladium(II) chloride copper(l) iodide 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  An alternative convergent synthesis of dendrimers with 2,5-diarylsilole at the core

  摘要：

  Dendrimers with 2,5-diarylsilole at the core are readily synthesized by the Ni-catalyzed reaction of 1, 1,2,2-tetramethyldisilane and 1,6-diynes having poly(benzyl ether)-dendron units. The dendrimers display, upon excitation of the silole ring, an emission at about 500 nm. The fluorescence quantum yield of the dendrimers increases with increasing the generation of the dendron units. In addition, upon excitation of dendron units in the periphery, the dendrimers also display an emission from the silole ring at the core through the energy transfer from the dendron units to the silole core within the dendrimers. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.037
• 作为产物：
  描述：

  溴乙烷 、 2,2-dipropargyl-1,3-propandiol 在 氢氧化钾 作用下， 以 二甲基亚砜 为溶剂， 反应 24.0h， 以57%的产率得到4,4-bis(ethoxymethyl)-1,6-heptadiyne
  参考文献：
  名称：

  An alternative convergent synthesis of dendrimers with 2,5-diarylsilole at the core

  摘要：

  Dendrimers with 2,5-diarylsilole at the core are readily synthesized by the Ni-catalyzed reaction of 1, 1,2,2-tetramethyldisilane and 1,6-diynes having poly(benzyl ether)-dendron units. The dendrimers display, upon excitation of the silole ring, an emission at about 500 nm. The fluorescence quantum yield of the dendrimers increases with increasing the generation of the dendron units. In addition, upon excitation of dendron units in the periphery, the dendrimers also display an emission from the silole ring at the core through the energy transfer from the dendron units to the silole core within the dendrimers. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.037