syn-vinylstibine | 356787-41-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: syn-vinylstibine
• 英文别名: ethenylstibine；vinylstibine
• CAS: 356787-41-2
• 化学式: C₂H₅Sb
• 分子量: 150.812
• InChiKey: JVFYBHATQWJKOX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.24
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  三正丁基氢锡 、 vinyldichlorostibine 在 duroquinone 作用下， 以 neat (no solvent) 为溶剂， 以53%的产率得到syn-vinylstibine
  参考文献：
  名称：

  Vibrational Spectra of Vinylarsine and Vinylstibine. An Experimental and Theoretical Study

  摘要：

  The infrared spectra (3200 to 600 cm(-1)) of gaseous vinylarsine and vinylstibine and their As-dideuterated and Sb-dideuterated derivative were recorded at 1 cm(-1) resolution. Both the infrared absorption bands of the syn and gauche conformers of the vinylarsine and vinylstibine were observed and assigned. The integrated intensities of isolated and overlapping vibrational bands were determined experimentally. Density functional theory calculations at the B3LYP/6-311G(d) level were performed to obtain the values of the harmonic vibrational frequencies. The results obtained are in good agreement with the experimental spectra and help in the assignment of the vibrational bands within the complex absorption region between 1100 and 600 cm(-1).

  DOI：

  10.1021/jp0145558

文献信息

• Legoupy; Lassalle; Guillemin, Inorganic Chemistry, 1995, vol. 34, # 6, p. 1466 - 1471
  作者：Legoupy、Lassalle、Guillemin、Métail、Senio、Pfister-Guillouzo

  DOI：——

  日期：——