| 1387006-99-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1387006-99-6
• 化学式: C₁₈H₁₈N₂O
• 分子量: 278.354
• InChiKey: DFFHLENULCOWTI-KGLIPLIRSA-N

反应信息

• 作为反应物：
  描述：

  在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 13.0h， 生成 2-[(10,10-dimethyl-5-phenyl-6-azatricyclo[7.1.1.0(2,7)]undeca-2(7),3,5-trien-8-ylimino)methyl]phenol
  参考文献：
  名称：

  A pineno-salen type catalyst for the enantioselective Nozaki–Hiyama–Kishi reaction

  摘要：

  A new class of pineno-salen type ligands 10, 11, 17, 20, 23, and 24 has been developed. The catalyst formed from chromium(II)-10 promotes the enantioselective Nozaki-Hiyama-Kishi allylation of alkyl and aryl aldehydes using allyl bromide. Notably, the asymmetric addition of vinyl halide to benzaldehyde was achieved with 24% ee. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2012.05.012
• 作为产物：
  描述：

  (5S,7R)-6,6-dimethyl-2-phenyl-5,7-methanoquinolin-8(5H)-one 在 盐酸羟胺 、 sodium acetate 作用下， 以 乙醇 、 水 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  A pineno-salen type catalyst for the enantioselective Nozaki–Hiyama–Kishi reaction

  摘要：

  A new class of pineno-salen type ligands 10, 11, 17, 20, 23, and 24 has been developed. The catalyst formed from chromium(II)-10 promotes the enantioselective Nozaki-Hiyama-Kishi allylation of alkyl and aryl aldehydes using allyl bromide. Notably, the asymmetric addition of vinyl halide to benzaldehyde was achieved with 24% ee. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2012.05.012