heptatriacontane-18,20-dione | 24514-85-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: heptatriacontane-18,20-dione
• 英文别名: Heptatriacontan-18,20-dion；18,20-Heptatriacontanedione
• CAS: 24514-85-0
• 化学式: C₃₇H₇₂O₂
• 分子量: 548.977
• InChiKey: WYKDTBMIJGOJAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.6
• 重原子数：
  39
• 可旋转键数：
  34
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2914190090

反应信息

• 作为反应物：
  描述：

  heptatriacontane-18,20-dione 在 羟胺 、 potassium carbonate 、 4-甲基-2-戊酮 作用下， 生成 19-octadecyl-heptatriacontane-18,20-dione dioxime
  参考文献：
  名称：

  Toubiana, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1959, vol. 248, p. 247,248

  摘要：

  DOI：
• 作为产物：
  描述：

  2-十九烷酮 、 硬脂酸乙酯 在 乙醚 、 sodium amide 作用下， 生成 heptatriacontane-18,20-dione
  参考文献：
  名称：

  Toubiana, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1959, vol. 248, p. 247,248

  摘要：

  DOI：

文献信息

• Zinc borate, and production method and use thereof
  申请人：——

  公开号：US20030030042A1

  公开（公告）日：2003-02-13

  A zinc borate having a particular crystallite size and containing very little sodium components and a method of preparing the same. The zinc borate has a particular chemical composition, has a crystallite size of not smaller than 40 nm as found from diffraction peaks of indexes of planes of (020), (101) and (200) in the X-ray diffraction image (Cu-k&agr;) and contains sodium components in amounts of not larger than 100 ppm as measured by the atomic absorptiometric method.

  一种具有特定晶粒尺寸且含有极少钠成分的锌硼酸盐及其制备方法。该锌硼酸盐具有特定的化学组成，其晶粒尺寸不小于40纳米，可以从X射线衍射图像（Cu-kα）的（020）、（101）和（200）平面的衍射峰中发现，并且钠成分的含量不超过100 ppm，由原子吸收光谱法测量。
• Beta-diketone and hydrotalcite stabilizer compositions for halogen-containing polymers and polymer compositions containing the same
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0063180A1

  公开（公告）日：1982-10-27

  Stabilizer compositions for halogen-containing polymers are provided composed of a β-diketone having the formula: wherein: R1 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR,, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and R2 is selected from the group consisting of hydrogen; hydroxyl; hydrocarbon having from one to about eighteen carbon atoms and such hydrocarbon groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR,, ester COOR1, alkyl and alkoxycarbonyl having from one to about eighteen carbon atoms; and if Z is R2 or n is 1 to 3, then no more than one R2 is hydrogen; one R1 and one R2 or two R2 may be linked together as an alkylene group to form a cyclic or ring structure; n is a number from 0 to 3; and Z is selected from the group consisting of R2 and a polyvalent linking radical selected from the group consisting of a direct linkage between the polyvalent hydrocarbon R3; wherein: R3 is a polyvalent hydrocarbon group having from one to about eighteen carbon atoms; R4 and R5 are selected from the group consisting of hydrogen and hydrocarbon groups having from one to about eighteen carbon atoms; and R4 and R5 may be linked together as an alkylene to form a cyclic or ring structure; X is -0- or -S-; m is 0 or 1; and R6 is selected from the group consisting of hydrogen, hydrocarbon having from one to about eighteen carbon atoms, and -R3-; as well as metal and organotin enolate salts thereof; and a hydrotalcite having the general formula: wherein x is a number from 0 to 0.5; A is CO3= or S04=, and m is a number representing the number of H20 in the molecule. The stabilizer compositions are effective in enhancing the resistance to deterioration by heat and light of halogen-containing polymers and especially polyvinyl halide resins. The β-diketone and hydrotalcite in these compositions exhibit a synergistic stabilizing effectiveness superior to either alone in like amount.

  提供了用于含卤聚合物的稳定剂组合物，该组合物由具有以下式子的 β-二酮组成： 其中 R1 选自氢、具有 1 至约 18 个碳原子的烃基和被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR、具有 1 至约 18 个碳原子的烷基和烷氧羰基烷基的基团取代的烃基组成的组，和 R2 选自由下列组成的组：氢；羟基；具有 1 至约 18 个碳原子的烃基，以及被 1 个或多个选自由下列组成的组的基团取代的烃基：卤素、羟基、烷氧基 OR、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基；如果 Z 是 R2 或 n 是 1 至 3，则不超过一个 R2 是氢； 一个 R1 和一个 R2 或两个 R2 可作为亚烷基连接在一起，形成环状或环状结构； n 是 0 至 3 的数字；以及 Z 选自 R2 和多价连接基组成的组，多价连接基选自以下组成的组 多价烃 R3； 其中 R3 是具有 1 至约 18 个碳原子的多价烃基； R4 和 R5 选自氢和具有 1 至约 18 个碳原子的烃基；R4 和 R5 可作为亚烷基连接在一起，形成环状或环状结构； X 是-0-或-S-； m 是 0 或 1；以及 R6 选自由氢、具有 1 至约 18 个碳原子的烃和-R3-组成的组； 及其金属盐和有机锡烯酸盐；以及通式为 其中 x 是 0 至 0.5 的数字； A 是 CO3= 或 S04=，以及 m 是代表分子中 H20 数量的数字。 这些稳定剂组合物能有效提高含卤聚合物，特别是聚卤乙烯树脂的耐热和耐光劣化性能。这些组合物中的β-二酮和氢滑石具有协同稳定效果，其效果优于单独使用相同数量的其中一种。
• Synthetic resin composition having reduced corrosion-causing tendency and coloration
  申请人：Kyowa Chemical Industry Co., Ltd.

  公开号：EP0189899A2

  公开（公告）日：1986-08-06

  A synthetic resin composition having reduced corrosion-causing tendency and coloration, said composition comprising (A) 100 parts by weight of a synthetic resin containing halogen and/or an acidic substance, and (B) 0.001 to 50 parts by weight of a hydrotalcite solid solution represented by the following formula (1)wherein M2+1 represents at least one divalent metal cation, M2+2 represents at least one divalent metal cation, M3+ represents a trivalent metal cation, An- represents an anion having a valency of n, and x, yl, Y2 and m are positive numbers represented by the following expressions 0

  一种可降低腐蚀倾向和着色的合成树脂组合物，所述组合物包括：(A) 100 份（按重量计）含卤素和/或酸性物质的合成树脂，和(B) 0.001 至 50 份（按重量计）由下式（1）表示的氢滑石固溶体，其中 M2+1 代表至少一种二价金属阳离子，M2+2 代表至少一种二价金属阳离子，M3+ 代表一种三价金属阳离子，An- 代表一种化合价为 n 的阴离子，x、yl、Y2 和 m 为正数，用以下表达式表示 0
• Stabilized polyvinyl chloride resin composition
  申请人：KYOWA CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0256872A2

  公开（公告）日：1988-02-24

  Magnesium oxide is incorporated into a polyvinyl chloride resin composition comprising a polyvinyl chloride, a hydrotalcite, a β-diketone compound and an organic acid salt of zinc or a polyvinyl chloride resin composition comprising a polyvinyl chloride, a hydro­talcite and an organic tin compound. Bubbling as well as discoloration can be prevented in a molded article prepared from the polyvinyl chloride resin composition. Magnesium oxide having a specific surface area of at least 50 m²/g and an average secondary particle size smaller than 5 µm is preferably used.

  将氧化镁加入由聚氯乙烯、氢铝酸盐、β-二酮化合物和锌的有机酸盐组成的聚氯乙烯树脂组合物中，或加入由聚氯乙烯、氢铝酸盐和有机锡化合物组成的聚氯乙烯树脂组合物中。用聚氯乙烯树脂组合物制备的模塑制品可以防止起泡和变色。最好使用比表面积至少为 50 m²/g、平均二次粒径小于 5 µm 的氧化镁。
• Improving stability at moderate temperatures of motor vehicle components shaped from polyvinyl chloride resin compositions
  申请人：WITCO CORPORATION

  公开号：EP0331095A1

  公开（公告）日：1989-09-06

  Motor vehicle components are provided having an improved stability at moderate temperatures and shaped from polyvinyl chloride resin compositions, comprising a polyvinyl chloride resin, at least one heat stabilizer in a sufficient amount to impart heat processing stability, and a S-diketone in a sufficient amount to provide, after forming, stability at moderate temperatures not provided by any residual heat stabilizer, as well as polyvinyl chloride resin stabilizer compositions and polyvinyl chloride resin compositions containing such heat stabilizer compositions suitable for use in forming motor vehicle components, comprising at least one heat stabilizer and a β-diketone.

  本发明提供了在中等温度下具有更高的稳定性并由聚氯乙烯树脂组合物成型的汽车部件，聚氯乙烯树脂组合物包括聚氯乙烯树脂、至少一种足够量的热稳定剂以赋予热加工稳定性，以及一种足够量的S-二酮以在成型后提供任何残余热稳定剂所不提供的中等温度下的稳定性，以及聚氯乙烯树脂稳定剂组合物和含有这种热稳定剂组合物的聚氯乙烯树脂组合物、以及聚氯乙烯树脂稳定剂组合物和含有此类热稳定剂组合物的聚氯乙烯树脂组合物，适用于汽车部件的成型，该组合物包含至少一种热稳定剂和一种 β-二酮。